MS45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 08 12 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.5948 0.3734 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 25203 25203 25203 99999 99999 25264 25264 25264 99999 99999 25326 25326 25326 99999 99999 25387 25387 25387 99999 99999 25449 25449 25449 99999 99999 25572 25572 25572 99999 99999 25633 25633 25633 11.22 491.43 25695 25695 25695 11.27 490.32 25756 25756 25756 11.3 488.47 25818 25818 25818 11.33 490.92 25879 25879 25879 11.28 492.31 25941 25941 25941 11.29 487.13 26002 26002 26002 11.41 488.62 26064 26064 26064 11.45 489.02 26187 26187 26187 11.43 490.21 26248 26248 26248 11.49 491.72 26310 26310 26310 11.55 491.27 26371 26371 26371 11.46 490.55 26433 26433 26433 11.41 490.81 26494 26494 26494 11.33 489.0 26556 26556 26556 11.52 490.46 26617 26617 26617 11.39 488.72 26679 26679 26679 11.44 490.33 26802 26802 26802 11.54 491.9 26863 26863 26863 11.51 491.14 26925 26925 26925 11.66 490.4 26986 26986 26986 11.63 491.05 27048 27048 27048 11.62 490.42 27109 27109 27109 11.59 491.06 27171 27171 27171 11.71 492.98 27232 27232 27232 11.68 490.65 27294 27294 27294 11.69 488.29 27417 27417 27417 11.47 489.54 27478 27478 27478 11.42 490.24 27540 27540 27540 11.52 490.9 27601 27601 27601 11.48 488.5 27663 27663 27663 11.43 488.29 27724 27724 27724 11.64 490.26 27786 27786 27786 11.43 489.58 27847 27847 27847 11.33 488.02 27909 27909 27909 11.35 488.2 28032 28032 28032 11.43 483.04 28093 28093 28093 11.39 484.33 28155 28155 28155 11.28 485.14 28216 28216 28216 11.31 487.64 28278 28278 28278 11.37 487.85 28339 28339 28339 11.39 485.04 28401 28401 28401 11.31 485.57 28462 28462 28462 11.31 483.75 28524 28524 28524 11.3 485.82 28647 28647 28647 11.34 485.38 28708 28708 28708 11.46 485.58 28770 28770 28770 11.4 487.61 28831 28831 28831 11.45 485.32 28893 28893 28893 11.28 482.61 28954 28954 28954 11.33 479.46 29016 29016 29016 11.24 478.67 29077 29077 29077 11.56 485.79 29139 29139 29139 11.45 486.74 29262 29262 29262 11.56 489.68 29323 29323 29323 11.66 490.3 29385 29385 29385 11.57 488.92 29446 29446 29446 11.39 488.76 29508 29508 29508 11.59 489.1 29569 29569 29569 11.38 488.28 29631 29631 29631 11.36 489.18 29692 29692 29692 11.5 488.84 29754 29754 29754 11.44 488.27 29877 29877 29877 11.48 488.55 29938 29938 29938 11.32 486.54 30000 30000 30000 11.41 488.28 30061 30061 30061 11.39 488.46 30123 30123 30123 11.4 490.12 30184 30184 30184 11.45 491.24 30246 30246 30246 11.5 490.52 30307 30307 30307 11.54 491.14 30369 30369 30369 11.42 490.16 30492 30492 30492 11.51 491.4 30553 30553 30553 11.53 491.57 30615 30615 30615 11.57 490.65 30676 30676 30676 11.49 490.82 30738 30738 30738 11.53 490.0 30799 30799 30799 11.56 491.61 30861 30861 30861 11.42 490.94 30922 30922 30922 11.44 489.87 30984 30984 30984 11.55 490.05 31107 31107 31107 11.52 488.86 31168 31168 31168 11.57 490.61 31230 31230 31230 11.54 490.34 31291 31291 31291 11.67 491.32 31353 31353 31353 11.53 490.56 31414 31414 31414 11.6 490.24 31476 31476 31476 11.58 490.72 31537 31537 31537 11.48 489.85 31599 31599 31599 11.5 490.49 31722 31722 31722 11.56 487.04 31783 31783 31783 11.58 487.24 31845 31845 31845 11.45 485.48 31906 31906 31906 11.41 484.49 31968 31968 31968 11.38 481.36 32029 32029 32029 11.34 482.64 32091 32091 32091 11.35 482.54 32152 32152 32152 11.37 480.96 32214 32214 32214 11.37 484.14 32337 32337 32337 11.41 484.8 32398 32398 32398 11.46 485.12 32460 32460 32460 11.44 485.24 32521 32521 32521 11.45 486.26 32583 32583 32583 11.45 485.61 32644 32644 32644 11.3 485.55 32706 32706 32706 11.51 484.71 32767 32767 32767 11.42 487.7 32829 32829 32829 11.41 489.82 32952 32952 32952 11.46 488.83 33013 33013 33013 11.39 486.65 33075 33075 33075 11.37 485.38 33136 33136 33136 11.5 489.59 33198 33198 33198 11.42 489.43 33259 33259 33259 11.55 488.58 33321 33321 33321 11.56 490.07 33382 33382 33382 11.43 487.54 33444 33444 33444 11.47 491.77 33567 33567 33567 11.52 489.82 33628 33628 33628 11.41 491.42 33690 33690 33690 11.53 491.45 33751 33751 33751 11.56 490.64 33813 33813 33813 11.6 491.22 33874 33874 33874 11.56 490.37 33936 33936 33936 11.37 493.85 33997 33997 33997 11.46 492.98 34059 34059 34059 11.45 491.03 34182 34182 34182 11.47 492.1 34243 34243 34243 11.49 492.18 34305 34305 34305 11.43 493.27 34366 34366 34366 11.51 492.07 34428 34428 34428 11.6 492.18 34489 34489 34489 11.43 491.68 34551 34551 34551 11.38 493.43 34612 34612 34612 11.41 490.16 34674 34674 34674 11.49 489.29 34797 34797 34797 11.5 490.81 34858 34858 34858 11.58 489.66 34920 34920 34920 11.44 491.63 34981 34981 34981 11.53 491.0 35043 35043 35043 11.65 490.74 35104 35104 35104 11.79 491.47 35166 35166 35166 11.58 491.4 35227 35227 35227 11.59 490.3 35289 35289 35289 11.63 491.48 35412 35412 35412 11.64 491.42 35473 35473 35473 11.65 491.23 35535 35535 35535 11.63 493.28 35596 35596 35596 11.64 490.69 35658 35658 35658 11.7 492.15 35719 35719 35719 11.52 490.6 35781 35781 35781 11.67 492.44 35842 35842 35842 11.57 490.58 35904 35904 35904 11.57 492.98 36027 36027 36027 11.69 490.73 36088 36088 36088 11.56 491.14 36150 36150 36150 11.54 490.53 36211 36211 36211 11.59 492.0 36273 36273 36273 11.5 490.71 36334 36334 36334 11.57 490.89 36396 36396 36396 11.58 492.03 36457 36457 36457 11.59 490.08 36519 36519 36519 11.56 490.71 36642 36642 36642 11.52 491.49 36703 36703 36703 11.45 489.63 36765 36765 36765 11.58 491.72 36826 36826 36826 11.42 491.37 36888 36888 36888 11.52 490.63 36949 36949 36949 11.62 492.18 37011 37011 37011 11.54 491.92 37072 37072 37072 11.6 491.26 37134 37134 37134 11.59 491.27 37257 37257 37257 11.4 492.51 37318 37318 37318 11.44 493.06 37380 37380 37380 11.45 491.61 37441 37441 37441 11.63 492.5 37503 37503 37503 11.5 491.71 37564 37564 37564 11.45 491.4 37626 37626 37626 11.44 492.77 37688 37688 37688 11.4 492.18 37749 37749 37749 11.35 492.9 37872 37872 37872 11.51 492.67 37934 37934 37934 11.39 493.62 37995 37995 37995 11.33 494.42 38057 38057 38057 11.45 494.34 38118 38118 38118 11.59 495.88 38180 38180 38180 11.43 494.62 38241 38241 38241 11.57 495.69 38303 38303 38303 11.36 493.35 38364 38364 38364 11.38 492.74 38487 38487 38487 11.44 489.78 38549 38549 38549 11.49 490.05 38610 38610 38610 11.4 492.12 38672 38672 38672 11.51 492.61 38733 38733 38733 11.56 493.59 38795 38795 38795 11.49 491.95 38856 38856 38856 11.48 492.68 38918 38918 38918 11.52 492.39 38979 38979 38979 11.5 493.95 39102 39102 39102 11.44 491.41 39164 39164 39164 11.4 491.76 39225 39225 39225 11.43 490.4 39287 39287 39287 11.44 490.4 39348 39348 39348 11.4 488.53 39410 39410 39410 11.32 489.54 39471 39471 39471 11.5 489.8 39533 39533 39533 11.45 490.31 39594 39594 39594 11.45 490.12 39717 39717 39717 11.52 491.0 39779 39779 39779 11.56 492.27 39840 39840 39840 11.51 490.97 39902 39902 39902 11.59 491.03 39963 39963 39963 11.56 491.38 40025 40025 40025 11.47 490.6 40086 40086 40086 11.36 492.28 40148 40148 40148 11.33 492.23 40209 40209 40209 11.33 490.15 40332 40332 40332 11.44 494.1 40394 40394 40394 11.48 492.62 40455 40455 40455 11.4 493.65 40517 40517 40517 11.49 494.24 40578 40578 40578 11.33 493.23 40640 40640 40640 11.41 490.6 40701 40701 40701 11.37 491.43 40763 40763 40763 11.52 491.53 40824 40824 40824 11.34 492.41 40947 40947 40947 11.51 492.44 41009 41009 41009 11.52 491.2 41070 41070 41070 11.53 492.58 41132 41132 41132 11.57 492.63 41193 41193 41193 11.5 491.62 41255 41255 41255 11.39 490.6 41316 41316 41316 11.44 492.74 41378 41378 41378 11.4 491.27 41439 41439 41439 11.54 491.15 41562 41562 41562 11.46 493.18 41624 41624 41624 11.44 493.61 41685 41685 41685 11.53 490.55 41747 41747 41747 11.51 491.31 41808 41808 41808 11.5 491.8 41870 41870 41870 11.55 490.88 41931 41931 41931 11.58 491.23 41993 41993 41993 11.65 491.57 42054 42054 42054 11.61 491.8 42177 42177 42177 11.55 490.5 42239 42239 42239 11.49 489.93 42300 42300 42300 11.57 490.21 42362 42362 42362 11.46 493.25 42423 42423 42423 11.53 492.78 42485 42485 42485 11.63 492.9 42546 42546 42546 11.55 493.12 42608 42608 42608 11.52 493.47 42669 42669 42669 11.58 492.58 42792 42792 42792 11.51 491.71 42854 42854 42854 11.57 493.59 42915 42915 42915 11.71 493.17 42977 42977 42977 11.73 492.15 43038 43038 43038 11.68 493.86 43100 43100 43100 11.79 493.42 43161 43161 43161 11.7 491.85 43223 43223 43223 11.85 493.28 43284 43284 43284 11.58 492.13 43407 43407 43407 11.54 492.51 43469 43469 43469 11.48 492.04 43530 43530 43530 11.68 492.28 43592 43592 43592 11.6 491.85 43653 43653 43653 11.53 491.37 43715 43715 43715 11.61 491.0 43776 43776 43776 11.61 491.96 43838 43838 43838 11.62 492.47 43899 43899 43899 11.57 492.01 44022 44022 44022 11.56 491.24 44084 44084 44084 11.43 491.7 44145 44145 44145 11.51 492.17 44207 44207 44207 11.71 492.66 44268 44268 44268 11.64 492.01 44330 44330 44330 11.71 490.96 44391 44391 44391 11.64 490.64 44453 44453 44453 11.69 491.48 44514 44514 44514 11.54 491.15 44637 44637 44637 11.58 490.94 44699 44699 44699 11.78 491.12 44760 44760 44760 11.64 491.25 44822 44822 44822 11.71 490.5 44883 44883 44883 11.7 491.32 44945 44945 44945 11.7 491.64 45006 45006 45006 11.49 490.39 45068 45068 45068 11.65 490.67 45129 45129 45129 11.5 489.82 45252 45252 45252 11.56 489.91 45314 45314 45314 11.58 490.02 45375 45375 45375 11.62 490.21 45437 45437 45437 11.46 490.67 45498 45498 45498 11.51 489.95 45560 45560 45560 11.46 488.92 45621 45621 45621 11.55 489.15 45683 45683 45683 11.4 488.54 45744 45744 45744 11.43 489.08 45867 45867 45867 11.46 489.97 45929 45929 45929 11.5 490.53 45990 45990 45990 11.51 488.42 46052 46052 46052 11.54 488.27 46113 46113 46113 11.53 489.69 46175 46175 46175 11.44 488.34 46236 46236 46236 11.45 489.89 46298 46298 46298 11.41 489.37 46359 46359 46359 11.41 487.85 46482 46482 46482 11.3 489.55 46544 46544 46544 11.53 489.16 46605 46605 46605 11.33 489.45 46667 46667 46667 11.48 488.15 46728 46728 46728 11.38 488.57 46790 46790 46790 11.49 489.62 46851 46851 46851 11.42 488.64 46913 46913 46913 11.35 490.04 46974 46974 46974 11.42 490.25 47097 47097 47097 11.42 489.63 47159 47159 47159 11.35 489.18 47220 47220 47220 11.47 488.86 47282 47282 47282 11.49 490.45 47343 47343 47343 11.49 490.26 47405 47405 47405 11.38 488.6 47466 47466 47466 11.38 488.61 47528 47528 47528 11.4 489.75 47589 47589 47589 11.43 490.47 47712 47712 47712 11.54 491.16 47774 47774 47774 11.58 491.02 47835 47835 47835 11.5 489.51 47897 47897 47897 11.41 488.38 47958 47958 47958 11.4 488.94 48020 48020 48020 11.34 489.42 48081 48081 48081 11.3 486.08 48143 48143 48143 11.41 488.45 48204 48204 48204 11.44 486.96 48327 48327 48327 11.41 490.01 48389 48389 48389 11.56 488.95 48450 48450 48450 11.49 490.46 48512 48512 48512 11.66 489.19 48573 48573 48573 11.62 490.67 48635 48635 48635 11.54 489.52 48696 48696 48696 11.57 489.27 48758 48758 48758 11.56 489.3 48819 48819 48819 11.62 489.06 48942 48942 48942 11.55 489.97 49004 49004 49004 11.56 491.42 49065 49065 49065 11.42 491.03 49127 49127 49127 11.7 490.51 49188 49188 49188 11.68 490.92 49250 49250 49250 11.58 489.98 49311 49311 49311 11.57 490.69 49373 49373 49373 11.6 489.63 49434 49434 49434 11.68 490.07 49557 49557 49557 11.55 489.86 49619 49619 49619 11.54 490.73 49680 49680 49680 11.57 491.16 49742 49742 49742 11.45 490.6 49803 49803 49803 11.58 489.18 49865 49865 49865 11.47 490.34 49926 49926 49926 11.46 489.43 49988 49988 49988 11.48 489.07 50049 50049 50049 11.43 489.98 50172 50172 50172 11.52 489.71 50234 50234 50234 11.47 488.03 50295 50295 50295 11.34 487.69 50357 50357 50357 11.32 486.99 50418 50418 50418 11.38 487.5 50480 50480 50480 11.41 488.04 50541 50541 50541 11.4 488.58 50603 50603 50603 11.48 487.61 50664 50664 50664 11.62 488.0 50787 50787 50787 11.48 488.55 50849 50849 50849 11.3 488.46 50910 50910 50910 11.34 487.62 50972 50972 50972 11.39 487.56 51033 51033 51033 11.42 487.45 51095 51095 51095 11.28 484.3 51156 51156 51156 11.33 484.76 51218 51218 51218 11.26 485.52 51279 51279 51279 11.28 484.86 51402 51402 51402 11.3 486.11 51464 51464 51464 11.31 486.42 51525 51525 51525 11.28 486.18 51587 51587 51587 11.26 486.18 51648 51648 51648 11.31 485.38 51710 51710 51710 11.25 486.55 51771 51771 51771 11.35 485.46 51833 51833 51833 11.28 482.53 51894 51894 51894 11.24 485.49 52017 52017 52017 11.32 485.64 52079 52079 52079 11.22 484.69 52140 52140 52140 11.51 491.46 52202 52202 52202 11.24 491.97 52263 52263 52263 11.53 490.5 52325 52325 52325 11.55 489.25 52386 52386 52386 11.4 489.08 52448 52448 52448 11.34 489.4 52509 52509 52509 11.42 488.85 52632 52632 52632 11.41 489.66 52694 52694 52694 11.58 490.17 52755 52755 52755 11.44 490.2 52817 52817 52817 11.52 490.02 52878 52878 52878 11.46 490.83 52940 52940 52940 11.58 490.86 53001 53001 53001 11.36 490.97 53063 53063 53063 11.37 490.04 53124 53124 53124 11.38 489.17 53247 53247 53247 11.47 489.96 53309 53309 53309 11.35 487.43 53370 53370 53370 11.32 486.17 53432 53432 53432 11.24 486.02 53493 53493 53493 11.38 485.78 53555 53555 53555 11.21 486.1 53616 53616 53616 11.4 486.84 53678 53678 53678 11.46 487.66 53739 53739 53739 11.42 484.95 53862 53862 53862 11.43 485.19 53924 53924 53924 11.44 486.01 53985 53985 53985 11.34 484.19 54047 54047 54047 11.23 485.33