45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 08 16 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.9179 0.3534 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 25001 25001 25001 99999 99999 25063 25063 25063 99999 99999 25124 25124 25124 99999 99999 25186 25186 25186 99999 99999 25247 25247 25247 99999 99999 25309 25309 25309 11.67 488.15 25432 25432 25432 11.56 485.62 25493 25493 25493 11.61 487.23 25555 25555 25555 11.44 485.42 25616 25616 25616 11.75 485.38 25678 25678 25678 11.62 486.65 25739 25739 25739 11.66 486.85 25801 25801 25801 11.44 488.02 25862 25862 25862 11.51 488.26 25924 25924 25924 11.62 490.34 26047 26047 26047 11.57 489.14 26108 26108 26108 11.57 490.75 26170 26170 26170 11.56 490.83 26231 26231 26231 11.42 491.2 26293 26293 26293 11.72 488.77 26354 26354 26354 11.57 488.58 26416 26416 26416 11.68 490.39 26477 26477 26477 11.75 488.85 26539 26539 26539 11.7 489.27 26662 26662 26662 11.83 488.5 26723 26723 26723 11.65 491.17 26785 26785 26785 11.61 489.12 26846 26846 26846 11.65 488.8 26908 26908 26908 11.69 489.04 26969 26969 26969 11.63 489.43 27031 27031 27031 11.61 490.7 27092 27092 27092 11.45 487.86 27154 27154 27154 11.61 489.63 27277 27277 27277 11.68 487.61 27338 27338 27338 11.67 488.88 27400 27400 27400 11.54 488.59 27461 27461 27461 11.57 489.73 27523 27523 27523 11.69 489.55 27584 27584 27584 11.65 490.84 27646 27646 27646 11.64 490.01 27707 27707 27707 11.7 490.93 27769 27769 27769 11.76 489.44 27892 27892 27892 11.86 490.6 27953 27953 27953 11.6 489.17 28015 28015 28015 11.64 488.11 28076 28076 28076 11.69 489.56 28138 28138 28138 11.63 488.42 28199 28199 28199 11.5 488.96 28261 28261 28261 11.47 488.86 28322 28322 28322 11.51 488.83 28384 28384 28384 11.52 490.45 28507 28507 28507 11.5 489.46 28568 28568 28568 11.52 489.4 28630 28630 28630 11.62 489.24 28691 28691 28691 11.61 489.69 28753 28753 28753 11.65 489.74 28814 28814 28814 11.9 490.98 28876 28876 28876 12.05 490.92 28937 28937 28937 12.01 490.32 28999 28999 28999 11.83 489.8 29122 29122 29122 11.36 479.86 29183 29183 29183 11.49 479.47 29245 29245 29245 11.36 481.91 29306 29306 29306 11.4 484.58 29368 29368 29368 11.43 485.19 29429 29429 29429 11.41 486.73 29491 29491 29491 11.46 484.75 29552 29552 29552 11.23 484.73 29614 29614 29614 11.34 484.96 29737 29737 29737 11.29 483.12 29798 29798 29798 11.41 482.93 29860 29860 29860 11.25 483.82 29921 29921 29921 11.42 484.21 29983 29983 29983 11.41 486.09 30044 30044 30044 11.39 485.04 30106 30106 30106 11.36 483.23 30167 30167 30167 11.36 484.9 30229 30229 30229 11.54 488.06 30352 30352 30352 11.35 488.05 30413 30413 30413 11.44 486.98 30475 30475 30475 11.41 486.18 30536 30536 30536 11.46 487.09 30598 30598 30598 11.45 486.49 30659 30659 30659 11.44 486.67 30721 30721 30721 11.36 483.02 30782 30782 30782 11.17 484.65 30844 30844 30844 11.37 486.39 30967 30967 30967 11.32 487.83 31028 31028 31028 11.4 486.73 31090 31090 31090 11.51 485.8 31151 31151 31151 11.44 484.95 31213 31213 31213 11.45 484.89 31274 31274 31274 11.4 485.02 31336 31336 31336 11.5 485.58 31397 31397 31397 11.64 485.81 31459 31459 31459 11.48 486.36 31582 31582 31582 11.57 491.34 31643 31643 31643 11.78 489.05 31705 31705 31705 11.65 489.75 31766 31766 31766 11.62 489.54 31828 31828 31828 11.54 489.02 31889 31889 31889 11.65 489.82 31951 31951 31951 11.48 489.65 32012 32012 32012 11.64 491.12 32074 32074 32074 11.41 491.54 32197 32197 32197 11.44 491.31 32258 32258 32258 11.71 491.63 32320 32320 32320 11.57 489.02 32381 32381 32381 11.64 490.19 32443 32443 32443 11.53 491.24 32504 32504 32504 11.52 490.47 32566 32566 32566 11.57 490.7 32627 32627 32627 11.66 490.75 32689 32689 32689 11.49 489.88 32812 32812 32812 11.54 491.81 32873 32873 32873 11.5 490.09 32935 32935 32935 11.61 490.6 32996 32996 32996 11.59 490.66 33058 33058 33058 11.54 490.33 33119 33119 33119 11.52 489.53 33181 33181 33181 11.78 488.71 33242 33242 33242 11.57 490.75 33304 33304 33304 11.74 490.68 33427 33427 33427 11.64 491.45 33488 33488 33488 11.59 491.69 33550 33550 33550 11.64 491.21 33611 33611 33611 11.63 491.83 33673 33673 33673 11.75 492.27 33734 33734 33734 11.5 490.78 33796 33796 33796 11.6 490.92 33857 33857 33857 11.62 489.83 33919 33919 33919 11.69 491.75 34042 34042 34042 11.64 490.49 34103 34103 34103 11.55 490.95 34165 34165 34165 11.69 491.46 34226 34226 34226 11.55 490.69 34288 34288 34288 11.58 490.26 34349 34349 34349 11.49 491.31 34411 34411 34411 11.48 489.44 34472 34472 34472 11.65 492.14 34534 34534 34534 11.59 492.26 34657 34657 34657 11.48 491.16 34718 34718 34718 11.43 491.62 34780 34780 34780 11.44 490.51 34841 34841 34841 11.36 487.5 34903 34903 34903 11.26 485.47 34964 34964 34964 11.14 480.62 35026 35026 35026 11.08 479.54 35087 35087 35087 11.1 479.43 35149 35149 35149 11.17 479.34 35272 35272 35272 11.12 476.63 35333 35333 35333 11.12 477.58 35395 35395 35395 11.07 476.68 35456 35456 35456 11.22 476.16 35518 35518 35518 11.14 475.43 35579 35579 35579 11.11 477.16 35641 35641 35641 10.98 472.08 35702 35702 35702 10.97 469.36 35764 35764 35764 11.07 474.67 35887 35887 35887 11.04 474.43 35948 35948 35948 11.21 473.68 36010 36010 36010 11.12 474.06 36071 36071 36071 11.07 472.12 36133 36133 36133 11.13 474.24 36194 36194 36194 11.08 474.25 36256 36256 36256 10.85 469.03 36317 36317 36317 11.05 470.03 36379 36379 36379 10.91 467.09 36502 36502 36502 10.91 467.37 36563 36563 36563 10.85 467.73 36625 36625 36625 10.89 463.3 36686 36686 36686 10.88 463.2 36748 36748 36748 10.84 459.81 36809 36809 36809 10.8 460.18 36871 36871 36871 10.84 461.35 36932 36932 36932 10.74 460.03 36994 36994 36994 10.87 458.39 37117 37117 37117 11.0 457.94 37178 37178 37178 10.86 459.15 37240 37240 37240 10.96 458.81 37301 37301 37301 10.89 457.32 37363 37363 37363 10.75 455.14 37424 37424 37424 10.97 455.64 37486 37486 37486 10.9 457.38 37547 37547 37547 10.91 457.1 37609 37609 37609 11.01 460.72 37732 37732 37732 11.0 462.22 37793 37793 37793 11.04 461.54 37855 37855 37855 10.86 461.65 37916 37916 37916 11.11 462.47 37978 37978 37978 11.05 466.22 38039 38039 38039 11.03 464.15 38101 38101 38101 10.99 462.02 38162 38162 38162 10.97 463.74 38224 38224 38224 11.13 466.77 38347 38347 38347 11.12 466.95 38408 38408 38408 11.19 469.29 38470 38470 38470 11.12 474.91 38531 38531 38531 11.23 474.51 38593 38593 38593 11.25 474.82 38654 38654 38654 11.2 475.85 38716 38716 38716 11.17 476.47 38777 38777 38777 11.35 476.91 38839 38839 38839 11.23 478.27 38962 38962 38962 11.29 477.01 39023 39023 39023 11.24 477.91 39085 39085 39085 11.3 478.19 39146 39146 39146 11.2 477.98 39208 39208 39208 11.25 476.39 39269 39269 39269 11.14 476.3 39331 39331 39331 11.27 471.48 39392 39392 39392 11.2 473.21 39454 39454 39454 10.89 464.25 39577 39577 39577 10.91 461.55 39638 39638 39638 11.03 464.17 39700 39700 39700 11.13 476.43 39761 39761 39761 11.22 472.47 39823 39823 39823 10.96 468.65 39884 39884 39884 11.06 475.65 39946 39946 39946 11.2 473.87 40007 40007 40007 11.27 473.15 40069 40069 40069 11.34 478.28 40192 40192 40192 11.23 477.74 40253 40253 40253 11.12 470.0 40315 40315 40315 11.02 457.88 40376 40376 40376 11.05 462.78 40438 40438 40438 11.14 473.23 40499 40499 40499 11.1 468.47 40561 40561 40561 11.05 460.81 40622 40622 40622 10.85 462.78 40684 40684 40684 10.93 459.69 40807 40807 40807 10.87 460.21 40868 40868 40868 10.91 463.27 40930 40930 40930 11.06 465.41 40991 40991 40991 11.05 461.25 41053 41053 41053 11.02 470.71 41114 41114 41114 11.0 471.51 41176 41176 41176 11.12 473.22 41237 41237 41237 11.29 476.89 41299 41299 41299 11.06 471.64 41422 41422 41422 11.17 474.55 41483 41483 41483 11.25 479.9 41545 41545 41545 11.2 481.14 41606 41606 41606 11.22 478.08 41668 41668 41668 11.27 482.4 41729 41729 41729 11.22 484.19 41791 41791 41791 11.13 482.89 41852 41852 41852 11.07 481.74 41914 41914 41914 11.01 471.28 42037 42037 42037 10.85 463.94 42098 42098 42098 11.12 479.73 42160 42160 42160 11.29 483.88 42221 42221 42221 11.15 483.7 42283 42283 42283 11.22 484.35 42344 42344 42344 11.24 484.02 42406 42406 42406 11.17 484.17 42467 42467 42467 11.12 484.67 42529 42529 42529 11.16 485.41 42652 42652 42652 11.27 484.97 42713 42713 42713 11.26 485.18 42775 42775 42775 11.3 486.54 42836 42836 42836 11.28 486.07 42898 42898 42898 11.25 484.31 42959 42959 42959 11.26 482.37 43021 43021 43021 11.29 481.18 43082 43082 43082 11.12 474.23 43144 43144 43144 11.1 466.91 43267 43267 43267 11.1 466.7 43328 43328 43328 10.96 462.22 43390 43390 43390 10.94 460.83 43451 43451 43451 11.02 457.84 43513 43513 43513 10.93 456.01 43574 43574 43574 10.94 454.19 43636 43636 43636 10.72 454.64 43697 43697 43697 10.72 458.22 43759 43759 43759 10.89 459.76 43882 43882 43882 10.96 460.9 43943 43943 43943 11.0 467.07 44005 44005 44005 11.03 464.39 44066 44066 44066 11.22 476.17 44128 44128 44128 11.24 477.27 44189 44189 44189 11.33 476.3 44251 44251 44251 11.23 477.26 44312 44312 44312 11.28 480.87 44374 44374 44374 11.34 481.06 44497 44497 44497 11.05 464.71 44558 44558 44558 11.18 470.71 44620 44620 44620 11.24 471.48 44681 44681 44681 11.2 478.47 44743 44743 44743 11.19 481.47 44804 44804 44804 11.23 475.81 44866 44866 44866 11.16 477.72 44927 44927 44927 11.2 476.95 44989 44989 44989 11.16 480.82 45112 45112 45112 11.18 482.38 45173 45173 45173 11.22 473.52 45235 45235 45235 10.95 468.44 45296 45296 45296 10.89 467.34 45358 45358 45358 10.88 468.25 45419 45419 45419 10.93 469.25 45481 45481 45481 10.85 466.85 45542 45542 45542 11.0 468.08 45604 45604 45604 10.96 471.01 45727 45727 45727 10.85 473.83 45788 45788 45788 10.9 471.49 45850 45850 45850 10.95 469.63 45911 45911 45911 11.01 474.08 45973 45973 45973 11.08 475.21 46034 46034 46034 11.03 475.1 46096 46096 46096 11.15 474.36 46157 46157 46157 11.08 469.99 46219 46219 46219 11.14 470.33 46342 46342 46342 11.03 470.13 46403 46403 46403 10.95 469.78 46465 46465 46465 11.05 469.15 46526 46526 46526 11.08 469.36 46588 46588 46588 11.19 470.32 46649 46649 46649 11.18 468.62 46711 46711 46711 10.98 468.55 46772 46772 46772 11.1 468.63 46834 46834 46834 11.05 467.98 46957 46957 46957 11.09 466.97 47018 47018 47018 11.1 465.4 47080 47080 47080 11.11 464.28 47141 47141 47141 11.08 467.39 47203 47203 47203 11.11 468.97 47264 47264 47264 11.13 469.66 47326 47326 47326 11.05 469.25 47387 47387 47387 11.13 470.4 47449 47449 47449 11.23 470.57 47572 47572 47572 11.16 471.38 47633 47633 47633 11.26 471.38 47695 47695 47695 11.06 470.77 47756 47756 47756 11.12 466.74 47818 47818 47818 11.1 466.06 47879 47879 47879 11.06 472.62 47941 47941 47941 11.1 476.94 48002 48002 48002 11.03 480.09 48064 48064 48064 11.22 476.2 48187 48187 48187 11.03 476.88 48248 48248 48248 11.24 482.85 48310 48310 48310 11.16 477.9 48372 48372 48372 11.05 473.02 48433 48433 48433 11.19 473.95 48495 48495 48495 11.28 481.1 48556 48556 48556 11.04 481.49 48618 48618 48618 11.13 477.1 48679 48679 48679 11.26 478.7 48802 48802 48802 11.05 481.52 48864 48864 48864 11.15 480.42 48925 48925 48925 11.31 480.28 48987 48987 48987 11.14 479.79 49048 49048 49048 11.28 479.85 49110 49110 49110 11.13 479.96 49171 49171 49171 11.27 480.42 49233 49233 49233 11.27 482.2 49294 49294 49294 11.35 478.43 49417 49417 49417 11.4 480.51 49479 49479 49479 11.16 478.4 49540 49540 49540 11.29 474.88 49602 49602 49602 11.1 474.66 49663 49663 49663 11.14 474.83 49725 49725 49725 11.16 474.73 49786 49786 49786 11.09 472.33 49848 49848 49848 11.08 473.97 49909 49909 49909 11.21 475.11 50032 50032 50032 11.2 475.7 50094 50094 50094 11.1 470.25 50155 50155 50155 10.88 458.2 50217 50217 50217 11.18 474.69 50278 50278 50278 11.53 490.22 50340 50340 50340 11.64 489.73 50401 50401 50401 11.64 489.24 50463 50463 50463 11.6 490.66 50524 50524 50524 11.53 490.33 50647 50647 50647 11.54 489.35 50709 50709 50709 11.58 488.99 50770 50770 50770 11.64 489.53 50832 50832 50832 11.49 488.32 50893 50893 50893 11.61 489.03 50955 50955 50955 11.52 489.02 51016 51016 51016 11.54 489.76 51078 51078 51078 11.55 488.91 51139 51139 51139 11.7 490.47 51262 51262 51262 11.55 489.21 51324 51324 51324 11.64 489.39 51385 51385 51385 11.72 490.27 51447 51447 51447 11.62 490.13 51508 51508 51508 11.7 489.36 51570 51570 51570 11.86 489.09 51631 51631 51631 11.74 488.67 51693 51693 51693 11.81 487.55 51754 51754 51754 11.59 487.82 51877 51877 51877 11.54 487.22 51939 51939 51939 11.56 487.02 52000 52000 52000 11.57 485.84 52062 52062 52062 11.57 488.09 52123 52123 52123 11.48 486.59 52185 52185 52185 11.42 484.22 52246 52246 52246 11.42 485.33 52308 52308 52308 11.47 485.36 52369 52369 52369 11.43 483.67 52492 52492 52492 11.35 484.23 52554 52554 52554 11.34 485.39 52615 52615 52615 11.44 487.37 52677 52677 52677 11.4 488.67 52738 52738 52738 11.29 485.26 52800 52800 52800 11.55 485.67 52861 52861 52861 11.41 486.53 52923 52923 52923 11.23 484.88 52984 52984 52984 11.28 484.91