45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 13 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.9467 0.2892 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 64996 64996 64996 11.57 489.35 65119 65119 65119 11.53 484.86 65180 65180 65180 11.47 485.45 65242 65242 65242 11.7 484.37 65303 65303 65303 11.71 484.86 65365 65365 65365 11.67 485.95 65426 65426 65426 11.82 485.56 65488 65488 65488 11.8 486.87 65549 65549 65549 11.8 488.54 65611 65611 65611 11.75 488.8 65734 65734 65734 11.77 491.19 65795 65795 65795 11.67 489.06 65857 65857 65857 11.76 486.41 65918 65918 65918 11.67 489.98 65980 65980 65980 11.54 487.97 66041 66041 66041 11.42 475.58 66103 66103 66103 11.42 486.43 66164 66164 66164 11.16 470.15 66226 66226 66226 10.99 471.81 66349 66349 66349 11.13 472.9 66410 66410 66410 11.14 476.28 66472 66472 66472 11.19 474.31 66533 66533 66533 11.09 472.23 66595 66595 66595 11.07 470.75 66656 66656 66656 10.97 470.45 66718 66718 66718 11.16 469.1 66779 66779 66779 11.04 468.55 66841 66841 66841 11.16 467.76 66964 66964 66964 10.91 463.82 67025 67025 67025 10.98 465.22 67087 67087 67087 11.15 467.2 67148 67148 67148 11.06 467.98 67210 67210 67210 11.16 470.63 67271 67271 67271 11.11 468.86 67333 67333 67333 11.08 471.54 67394 67394 67394 11.23 472.22 67456 67456 67456 11.26 470.05 67579 67579 67579 11.05 466.92 67640 67640 67640 11.14 469.16 67702 67702 67702 11.19 471.95 67763 67763 67763 11.18 470.69 67825 67825 67825 11.03 471.21 67886 67886 67886 11.08 470.4 67948 67948 67948 11.1 467.43 68009 68009 68009 11.13 470.05 68071 68071 68071 11.37 480.01 68194 68194 68194 11.22 486.22 68255 68255 68255 11.42 485.47 68317 68317 68317 11.41 483.47 68378 68378 68378 11.17 481.16 68440 68440 68440 11.29 483.5 68501 68501 68501 11.19 480.95 68563 68563 68563 11.18 477.27 68624 68624 68624 11.42 478.43 68686 68686 68686 11.3 481.24 68809 68809 68809 11.05 469.02 68870 68870 68870 11.07 467.8 68932 68932 68932 10.89 467.57 68993 68993 68993 11.0 467.7 69055 69055 69055 11.09 467.28 69116 69116 69116 11.07 468.59 69178 69178 69178 10.91 468.06 69239 69239 69239 11.19 473.41 69301 69301 69301 11.3 480.36 69424 69424 69424 11.21 478.2 69485 69485 69485 11.21 476.66 69547 69547 69547 11.0 471.82 69608 69608 69608 11.36 482.64 69670 69670 69670 11.11 477.89 69731 69731 69731 11.31 484.51 69793 69793 69793 11.15 484.84 69854 69854 69854 11.35 484.84 69916 69916 69916 11.11 483.57 70039 70039 70039 11.18 488.4 70100 70100 70100 11.32 488.76 70162 70162 70162 11.21 488.16 70223 70223 70223 11.2 484.22 70285 70285 70285 11.15 479.94 70346 70346 70346 11.33 479.66 70408 70408 70408 11.42 490.91 70469 70469 70469 11.48 490.59 70531 70531 70531 11.27 486.2 70654 70654 70654 11.17 474.21 70715 70715 70715 11.33 476.94 70777 70777 70777 11.13 474.53 70838 70838 70838 11.2 473.48 70900 70900 70900 11.03 471.37 70961 70961 70961 11.19 475.2 71023 71023 71023 11.17 474.11 71084 71084 71084 10.93 475.4 71146 71146 71146 11.3 479.68 71269 71269 71269 11.33 487.04 71330 71330 71330 11.53 489.19 71392 71392 71392 11.42 487.28 71453 71453 71453 11.52 486.86 71515 71515 71515 11.52 485.47 71576 71576 71576 11.38 483.66 71638 71638 71638 11.46 482.93 71699 71699 71699 11.42 482.6 71761 71761 71761 11.42 483.11 71884 71884 71884 11.5 484.1 71945 71945 71945 11.44 482.73 72007 72007 72007 11.45 484.37 72068 72068 72068 11.51 484.78 72130 72130 72130 11.39 483.64 72191 72191 72191 11.39 485.47 72253 72253 72253 11.49 486.08 72314 72314 72314 11.53 489.14 72376 72376 72376 11.39 489.57 72499 72499 72499 11.5 489.14 72560 72560 72560 11.42 491.83 72622 72622 72622 11.44 490.06 72683 72683 72683 11.67 490.27 72745 72745 72745 11.49 489.58 72806 72806 72806 11.58 489.07 72868 72868 72868 11.52 490.31 72929 72929 72929 11.72 488.33 72991 72991 72991 11.58 489.08 73114 73114 73114 11.45 488.18 73175 73175 73175 11.53 487.16 73237 73237 73237 11.39 483.57 73298 73298 73298 11.58 484.93 73360 73360 73360 11.39 480.85 73421 73421 73421 11.33 475.4 73483 73483 73483 11.44 479.11 73544 73544 73544 11.32 481.07 73606 73606 73606 11.46 479.92 73729 73729 73729 11.26 478.92 73790 73790 73790 11.33 478.31 73852 73852 73852 11.33 479.05 73913 73913 73913 11.33 479.38 73975 73975 73975 11.38 479.55 74036 74036 74036 11.27 480.13 74098 74098 74098 11.43 482.73 74159 74159 74159 11.51 484.62 74221 74221 74221 11.63 486.02 74344 74344 74344 11.49 490.75 74405 74405 74405 11.75 491.4 74467 74467 74467 11.54 491.46 74528 74528 74528 11.33 487.71 74590 74590 74590 11.38 487.36 74651 74651 74651 11.39 488.77 74713 74713 74713 11.47 487.57 74774 74774 74774 11.4 488.36 74836 74836 74836 11.46 485.99 74959 74959 74959 11.25 483.58 75020 75020 75020 11.38 484.71 75082 75082 75082 11.37 484.89 75143 75143 75143 11.36 485.95 75205 75205 75205 11.36 485.56 75266 75266 75266 11.38 486.91 75328 75328 75328 11.39 485.78 75389 75389 75389 11.43 486.14 75451 75451 75451 11.5 487.56 75574 75574 75574 11.51 490.33 75635 75635 75635 11.49 488.02 75697 75697 75697 11.39 485.66 75758 75758 75758 11.6 483.99 75820 75820 75820 11.33 477.81 75881 75881 75881 11.23 472.73 75943 75943 75943 11.11 466.52 76004 76004 76004 11.29 470.45 76066 76066 76066 11.14 469.03 76189 76189 76189 11.13 471.2 76251 76251 76251 11.31 481.07 76312 76312 76312 11.47 488.73 76374 76374 76374 11.46 489.94 76435 76435 76435 11.47 486.93 76497 76497 76497 11.19 479.16 76558 76558 76558 11.22 479.07 76620 76620 76620 11.38 479.21 76681 76681 76681 11.18 479.15 76804 76804 76804 11.28 483.05 76866 76866 76866 11.4 486.65 76927 76927 76927 11.46 488.74 76989 76989 76989 11.45 488.37 77050 77050 77050 11.37 487.85 77112 77112 77112 11.37 486.37 77173 77173 77173 11.44 486.91 77235 77235 77235 11.44 487.02 77296 77296 77296 11.44 486.96 77419 77419 77419 11.47 487.22 77481 77481 77481 11.48 489.82 77542 77542 77542 11.39 488.71 77604 77604 77604 11.36 488.17 77665 77665 77665 11.34 485.68 77727 77727 77727 11.24 476.11 77788 77788 77788 11.16 470.3 77850 77850 77850 11.05 468.32 77911 77911 77911 11.13 468.97 78034 78034 78034 11.14 467.11 78096 78096 78096 10.97 467.67 78157 78157 78157 11.05 470.8 78219 78219 78219 11.04 469.54 78280 78280 78280 11.13 469.68 78342 78342 78342 11.26 469.7 78403 78403 78403 11.03 468.32 78465 78465 78465 11.17 467.96 78526 78526 78526 11.08 466.03 78649 78649 78649 11.11 467.18 78711 78711 78711 11.05 465.82 78772 78772 78772 11.05 467.31 78834 78834 78834 11.06 468.06 78895 78895 78895 11.13 469.02 78957 78957 78957 11.2 473.2 79018 79018 79018 11.19 476.62 79080 79080 79080 11.4 483.01 79141 79141 79141 11.29 484.68 79264 79264 79264 11.37 482.7 79326 79326 79326 11.35 485.4 79387 79387 79387 11.32 486.29 79449 79449 79449 11.38 487.08 79510 79510 79510 11.34 486.09 79572 79572 79572 11.37 486.97 79633 79633 79633 11.32 485.92 79695 79695 79695 11.63 486.24 79756 79756 79756 11.48 487.05 79879 79879 79879 11.49 486.92 79941 79941 79941 11.47 487.33 80002 80002 80002 11.53 486.63 80064 80064 80064 11.46 486.41 80125 80125 80125 11.42 480.29 80187 80187 80187 11.35 480.01 80248 80248 80248 11.4 479.14 80310 80310 80310 11.68 487.62 80371 80371 80371 11.61 490.04 80494 80494 80494 11.55 484.92 80556 80556 80556 11.36 483.02 80617 80617 80617 11.39 479.57 80679 80679 80679 11.38 482.46 80740 80740 80740 11.44 483.2 80802 80802 80802 11.49 484.95 80863 80863 80863 11.27 484.21 80925 80925 80925 11.35 485.34 80986 80986 80986 11.54 487.4 81109 81109 81109 11.39 487.45 81171 81171 81171 11.46 487.24 81232 81232 81232 11.53 487.7 81294 81294 81294 11.36 486.5 81355 81355 81355 11.45 488.12 81417 81417 81417 11.53 489.07 81478 81478 81478 11.37 489.14 81540 81540 81540 11.59 488.83 81601 81601 81601 11.39 487.68 81724 81724 81724 11.48 489.22 81786 81786 81786 11.45 489.12 81847 81847 81847 11.54 488.71 81909 81909 81909 11.54 489.21 81970 81970 81970 11.62 489.37 82032 82032 82032 11.56 489.31 82093 82093 82093 11.55 489.12 82155 82155 82155 11.56 489.59 82216 82216 82216 11.45 488.8 82339 82339 82339 11.52 489.39 82401 82401 82401 11.51 489.9 82462 82462 82462 11.47 489.89 82524 82524 82524 11.51 488.1 82585 82585 82585 11.34 485.9 82647 82647 82647 11.32 486.57 82708 82708 82708 11.37 486.89 82770 82770 82770 11.33 480.51 82831 82831 82831 11.41 486.97 82954 82954 82954 11.48 488.76 83016 83016 83016 11.39 488.98 83077 83077 83077 11.23 475.9 83139 83139 83139 11.06 466.82 83200 83200 83200 11.21 474.15 83262 83262 83262 11.24 474.44 83323 83323 83323 11.23 469.14 83385 83385 83385 11.42 478.84 83446 83446 83446 11.25 470.79 83569 83569 83569 11.33 472.01 83631 83631 83631 11.21 465.88 83692 83692 83692 11.24 474.36 83754 83754 83754 11.37 480.35 83815 83815 83815 11.47 481.78 83877 83877 83877 11.5 478.23 83938 83938 83938 11.27 479.13 84000 84000 84000 11.5 477.91 84061 84061 84061 11.38 474.36 84184 84184 84184 11.28 470.5 84246 84246 84246 11.14 465.49 84307 84307 84307 11.14 466.36 84369 84369 84369 10.98 461.07 84430 84430 84430 11.07 461.11 84492 84492 84492 11.0 463.32 84553 84553 84553 11.25 467.93 84615 84615 84615 11.25 466.66 84676 84676 84676 11.11 467.59 84799 84799 84799 11.02 461.21 84861 84861 84861 11.06 464.72 84922 84922 84922 11.13 467.86 84984 84984 84984 10.99 468.65 85045 85045 85045 11.06 469.62 85107 85107 85107 11.1 475.05 85168 85168 85168 11.27 480.94 85230 85230 85230 11.22 479.49 85291 85291 85291 11.19 478.37 85414 85414 85414 11.11 478.48 85476 85476 85476 10.92 467.67 85537 85537 85537 11.01 473.92 85599 85599 85599 11.13 474.65 85660 85660 85660 11.01 473.3 85722 85722 85722 11.31 478.43 85783 85783 85783 11.1 475.22 85845 85845 85845 11.14 473.88 85906 85906 85906 11.26 478.8 86029 86029 86029 11.15 468.72 86091 86091 86091 11.29 477.96 86152 86152 86152 11.41 488.56 86214 86214 86214 11.35 487.32 86275 86275 86275 11.37 481.96 86337 86337 86337 11.42 480.35 86398 86398 86398 11.32 482.8 86460 86460 86460 11.41 486.76 86521 86521 86521 11.52 488.59 86644 86644 86644 11.42 490.0 86706 86706 86706 11.39 490.11 86767 86767 86767 11.52 488.09 86829 86829 86829 11.4 489.11 86890 86890 86890 11.31 487.0 86952 86952 86952 11.45 485.69 87014 87014 87014 11.33 484.01 87075 87075 87075 11.54 484.84 87137 87137 87137 11.42 483.9 87260 87260 87260 11.45 486.78 87321 87321 87321 11.5 484.51 87383 87383 87383 11.51 485.64 87444 87444 87444 11.44 485.14 87506 87506 87506 11.45 485.68 87567 87567 87567 11.46 485.79 87629 87629 87629 11.41 485.15 87690 87690 87690 11.39 484.98 87752 87752 87752 11.55 485.62 87875 87875 87875 11.37 485.78 87936 87936 87936 11.38 486.26 87998 87998 87998 11.52 485.54 88059 88059 88059 11.48 484.54 88121 88121 88121 11.41 484.77 88182 88182 88182 11.39 483.32 88244 88244 88244 11.54 484.19 88305 88305 88305 11.52 483.72 88367 88367 88367 11.63 485.02 88490 88490 88490 11.49 483.32 88551 88551 88551 11.51 483.17 88613 88613 88613 11.65 481.52 88674 88674 88674 11.35 475.36 88736 88736 88736 11.3 477.63 88797 88797 88797 11.39 482.16 88859 88859 88859 11.33 481.82 88920 88920 88920 11.25 480.26 88982 88982 88982 11.15 474.95 89105 89105 89105 11.47 483.04 89166 89166 89166 11.41 482.84 89228 89228 89228 11.25 480.29 89289 89289 89289 11.31 478.13 89351 89351 89351 11.26 473.83 89412 89412 89412 11.26 473.37 89474 89474 89474 11.23 473.15 89535 89535 89535 11.17 470.83 89597 89597 89597 11.06 468.81 89720 89720 89720 11.25 468.34 89781 89781 89781 11.21 470.95 89843 89843 89843 11.2 472.6 89904 89904 89904 11.14 472.37 89966 89966 89966 11.21 472.0 90027 90027 90027 11.22 474.94 90089 90089 90089 11.16 472.87 90150 90150 90150 11.13 469.54 90212 90212 90212 11.11 466.73 90335 90335 90335 11.1 460.59 90396 90396 90396 11.03 463.13 90458 90458 90458 10.98 461.42 90519 90519 90519 11.04 461.82 90581 90581 90581 10.98 460.81 90642 90642 90642 10.96 460.8 90704 90704 90704 11.04 459.42 90765 90765 90765 10.95 457.16 90827 90827 90827 10.92 455.25 90950 90950 90950 10.87 456.04 91011 91011 91011 11.06 462.69 91073 91073 91073 10.9 466.53 91134 91134 91134 11.03 465.71 91196 91196 91196 10.94 465.57 91257 91257 91257 10.99 465.48 91319 91319 91319 11.07 464.37 91380 91380 91380 11.0 464.11 91442 91442 91442 11.07 463.82 91565 91565 91565 10.99 465.01 91626 91626 91626 11.1 466.87 91688 91688 91688 11.27 466.05 91749 91749 91749 11.07 465.91 91811 91811 91811 10.95 465.85 91872 91872 91872 11.06 466.12 91934 91934 91934 10.92 466.62 91995 91995 91995 10.98 465.16 92057 92057 92057 11.09 466.66 92180 92180 92180 10.96 463.44 92241 92241 92241 11.11 474.57 92303 92303 92303 11.29 474.81 92364 92364 92364 11.12 471.36 92426 92426 92426 11.1 468.58 92487 92487 92487 10.96 469.36 92549 92549 92549 11.12 470.89 92610 92610 92610 11.11 475.8 92672 92672 92672 11.12 480.36 92795 92795 92795 11.04 466.93 92856 92856 92856 11.08 471.78 92918 92918 92918 11.16 473.42 92979 92979 92979 11.2 471.57 93041 93041 93041 11.16 470.4 93102 93102 93102 11.25 472.67 93164 93164 93164 11.14 469.71 93225 93225 93225 11.26 471.44 93287 93287 93287 11.18 465.0 93410 93410 93410 11.31 469.21 93471 93471 93471 11.26 467.78 93533 93533 93533 11.19 468.23 93594 93594 93594 11.38 484.03 93656 93656 93656 11.52 487.02 93717 93717 93717 11.35 484.43 93779 93779 93779 11.23 484.51 93840 93840 93840 11.51 483.74 93902 93902 93902 11.18 480.04 94025 94025 94025 11.26 483.52 94086 94086 94086 11.57 487.65 94148 94148 94148 11.39 488.39 94209 94209 94209 11.45 487.12 94271 94271 94271 11.46 486.99 94332 94332 94332 11.41 488.11 94394 94394 94394 11.51 487.05 94455 94455 94455 11.46 487.67 94517 94517 94517 11.59 486.81 94640 94640 94640 11.51 489.13 94701 94701 94701 11.49 488.92 94763 94763 94763 11.32 482.36 94824 94824 94824 11.06 468.72 94886 94886 94886 11.13 473.44 94947 94947 94947 11.35 481.06 95009 95009 95009 11.07 472.57 95070 95070 95070 11.1 470.77 95132 95132 95132 11.34 472.08 95255 95255 95255 11.7 488.65 95316 95316 95316 11.68 489.48 95378 95378 95378 11.57 488.35 95439 95439 95439 11.76 489.98 95501 95501 95501 11.64 489.57 95562 95562 95562 11.72 488.25 95624 95624 95624 11.74 490.35 95685 95685 95685 11.53 489.81 95747 95747 95747 11.62 488.87 95870 95870 95870 11.51 486.65 95931 95931 95931 11.49 487.72 95993 95993 95993 11.43 488.14 96054 96054 96054 11.54 485.85 96116 96116 96116 11.56 487.8 96177 96177 96177 11.64 487.68 96239 96239 96239 11.53 486.11 96300 96300 96300 11.58 486.39 96362 96362 96362 11.64 486.03 96485 96485 96485 11.58 487.29 96546 96546 96546 11.7 487.88 96608 96608 96608 11.69 486.27 96669 96669 96669 11.53 484.8 96731 96731 96731 11.69 485.34 96792 96792 96792 11.64 485.42 96854 96854 96854 11.78 486.41 96915 96915 96915 11.9 483.8