MS45 1001 Markus Jesswein, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany 1|HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-ECD instrument, integrated under usage of constant baseline PHILEAS 1 1 2023 09 27 2025 11 06 0 Mean sample time in UT seconds past midnight of flight date 4 1 1 1 1 99999 99999 99999 99999 Time_Start [s] Time_End [s] SF6 [ppt] CFC_12 [ppt] 25 ------------------------------------------------------------------------ Please inform the authors about the use of the data These are preliminary data and not for publication. Please adhere in all cases to the PHILEAS data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: TO-Mutter (UEA scales), J-256 (AGAGE network) Calibration Scales SF6 CFC_12 SIO-05 SIO-05 ------------------------------------------------------------------------ Instrument precision in [%] NaN NaN NaN NaN NaN NAN NAN 0.9122 0.2746 Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP NaN NaN NaN NaN NaN Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ SF6 data non-linearity below measurement precision. no correction applied F12 mixing ratio data has been corrected for detector non-linearity by applying a second order polynom: k = a0 + a1 * mr_F12 + a2 * mr_F12^2 coefficients: a0 = -0.04257; a1 = 1.04244; a2 = 0.00013 ------------------------------------------------------------------------ 2 UTC Time_Start Time_End SF6 CFC_12 [s] [s] [s] [ppt] [ppt] 27434 27434 27434 99999 99999 27495 27495 27495 99999 99999 27557 27557 27557 11.56 485.14 27680 27680 27680 11.55 487.69 27741 27741 27741 11.45 487.4 27803 27803 27803 11.52 488.79 27864 27864 27864 11.54 486.15 27926 27926 27926 11.42 486.81 27987 27987 27987 11.49 487.03 28049 28049 28049 11.51 487.48 28110 28110 28110 11.38 489.7 28172 28172 28172 11.48 489.56 28295 28295 28295 11.57 488.44 28356 28356 28356 11.72 489.16 28418 28418 28418 11.49 490.11 28479 28479 28479 11.68 490.53 28541 28541 28541 11.53 490.73 28602 28602 28602 11.58 489.26 28664 28664 28664 11.53 488.71 28725 28725 28725 11.5 488.3 28787 28787 28787 11.52 488.64 28910 28910 28910 11.65 486.68 28971 28971 28971 11.73 490.59 29033 29033 29033 11.59 488.53 29094 29094 29094 11.49 487.96 29156 29156 29156 11.47 489.02 29217 29217 29217 11.54 489.87 29279 29279 29279 11.42 490.09 29340 29340 29340 11.54 488.12 29402 29402 29402 11.55 488.17 29525 29525 29525 11.48 487.29 29586 29586 29586 11.52 487.45 29648 29648 29648 11.46 486.72 29709 29709 29709 11.49 486.32 29771 29771 29771 11.33 484.12 29832 29832 29832 11.45 485.19 29894 29894 29894 11.5 485.1 29955 29955 29955 11.47 486.63 30017 30017 30017 11.58 486.43 30140 30140 30140 11.47 482.9 30201 30201 30201 11.53 483.47 30263 30263 30263 11.6 484.11 30324 30324 30324 11.47 484.18 30386 30386 30386 11.53 481.53 30447 30447 30447 11.65 483.62 30509 30509 30509 11.64 484.01 30570 30570 30570 11.57 484.05 30632 30632 30632 11.63 486.38 30755 30755 30755 11.56 488.56 30816 30816 30816 11.7 487.42 30878 30878 30878 11.54 487.21 30939 30939 30939 11.54 486.24 31001 31001 31001 11.39 485.27 31062 31062 31062 11.47 486.44 31124 31124 31124 11.66 486.88 31185 31185 31185 11.57 487.38 31247 31247 31247 11.46 487.77 31370 31370 31370 11.51 487.99 31431 31431 31431 11.53 491.09 31493 31493 31493 11.69 489.86 31554 31554 31554 11.59 487.55 31616 31616 31616 11.61 485.51 31677 31677 31677 11.54 486.75 31739 31739 31739 11.72 487.24 31800 31800 31800 11.66 485.38 31862 31862 31862 11.71 484.68 31985 31985 31985 11.75 480.41 32046 32046 32046 11.63 480.06 32108 32108 32108 11.56 477.66 32169 32169 32169 11.43 478.96 32231 32231 32231 11.27 477.97 32292 32292 32292 11.27 476.14 32354 32354 32354 11.32 477.6 32415 32415 32415 11.18 476.3 32477 32477 32477 11.24 475.53 32600 32600 32600 11.13 475.56 32661 32661 32661 11.24 474.7 32723 32723 32723 11.23 475.17 32784 32784 32784 11.22 476.49 32846 32846 32846 11.05 476.53 32907 32907 32907 11.26 475.31 32969 32969 32969 11.08 475.98 33030 33030 33030 11.01 477.47 33092 33092 33092 11.02 478.65 33215 33215 33215 11.09 478.64 33276 33276 33276 11.13 478.89 33338 33338 33338 11.12 479.27 33399 33399 33399 11.15 479.3 33461 33461 33461 11.21 477.68 33522 33522 33522 11.06 477.44 33584 33584 33584 11.34 478.82 33645 33645 33645 11.13 478.77 33707 33707 33707 11.35 478.57 33830 33830 33830 11.17 478.56 33891 33891 33891 11.16 479.78 33953 33953 33953 11.19 478.98 34014 34014 34014 11.36 479.73 34076 34076 34076 11.26 481.36 34137 34137 34137 11.3 480.93 34199 34199 34199 11.28 480.55 34260 34260 34260 11.29 482.39 34322 34322 34322 11.19 480.8 34445 34445 34445 11.35 481.59 34506 34506 34506 11.22 479.29 34568 34568 34568 11.11 478.65 34629 34629 34629 11.17 477.6 34691 34691 34691 11.12 477.17 34752 34752 34752 11.28 477.98 34814 34814 34814 11.06 476.55 34875 34875 34875 11.24 477.93 34937 34937 34937 11.17 476.06 35060 35060 35060 11.16 477.6 35121 35121 35121 11.14 478.31 35183 35183 35183 11.25 477.3 35244 35244 35244 11.48 476.55 35306 35306 35306 11.19 478.06 35367 35367 35367 11.23 476.82 35429 35429 35429 11.18 476.71 35490 35490 35490 11.27 475.88 35552 35552 35552 11.18 476.06 35675 35675 35675 11.34 479.22 35736 35736 35736 11.13 477.67 35798 35798 35798 11.14 478.18 35859 35859 35859 11.3 479.48 35921 35921 35921 11.07 477.7 35982 35982 35982 11.27 478.61 36044 36044 36044 11.29 480.37 36105 36105 36105 11.29 480.09 36167 36167 36167 11.38 478.85 36290 36290 36290 11.35 481.52 36351 36351 36351 11.27 482.21 36413 36413 36413 11.38 480.61 36474 36474 36474 11.24 479.28 36536 36536 36536 11.38 479.52 36597 36597 36597 11.35 480.66 36659 36659 36659 11.47 481.68 36720 36720 36720 11.25 479.28 36782 36782 36782 11.37 478.07 36905 36905 36905 11.3 478.64 36966 36966 36966 11.32 478.06 37028 37028 37028 11.47 477.37 37089 37089 37089 11.49 478.48 37151 37151 37151 11.53 476.7 37212 37212 37212 11.4 479.57 37274 37274 37274 11.37 479.33 37335 37335 37335 11.38 479.02 37397 37397 37397 11.48 479.49 37520 37520 37520 11.37 478.88 37581 37581 37581 11.44 478.74 37643 37643 37643 11.43 480.27 37704 37704 37704 11.44 480.4 37766 37766 37766 11.29 479.06 37827 37827 37827 11.25 478.65 37889 37889 37889 11.22 475.86 37950 37950 37950 11.36 477.43 38012 38012 38012 11.35 478.76 38135 38135 38135 11.29 478.62 38196 38196 38196 11.27 476.03 38258 38258 38258 11.41 477.13 38319 38319 38319 11.3 475.89 38381 38381 38381 11.26 476.05 38442 38442 38442 11.27 474.29 38504 38504 38504 11.28 474.69 38565 38565 38565 11.4 476.57 38627 38627 38627 11.22 478.57 38750 38750 38750 11.15 475.27 38811 38811 38811 11.18 472.67 38873 38873 38873 11.17 473.66 38934 38934 38934 11.39 475.38 38996 38996 38996 11.33 478.1 39057 39057 39057 11.17 479.97 39119 39119 39119 11.43 481.04 39180 39180 39180 11.44 482.53 39242 39242 39242 11.43 486.03 39365 39365 39365 11.35 481.72 39426 39426 39426 11.25 483.12 39488 39488 39488 11.43 484.73 39549 39549 39549 11.42 484.11 39611 39611 39611 11.41 482.68 39672 39672 39672 11.28 483.68 39734 39734 39734 11.25 480.83 39795 39795 39795 11.25 482.41 39857 39857 39857 11.34 480.47 39980 39980 39980 11.11 475.81 40041 40041 40041 11.28 476.72 40103 40103 40103 11.32 477.09 40164 40164 40164 11.26 474.89 40226 40226 40226 11.18 475.67 40287 40287 40287 11.32 478.25 40349 40349 40349 11.35 485.67 40410 40410 40410 11.39 483.73 40472 40472 40472 11.14 472.96 40595 40595 40595 11.19 475.42 40656 40656 40656 11.06 468.35 40718 40718 40718 11.23 472.8 40779 40779 40779 11.39 471.65 40841 40841 40841 11.18 469.99 40902 40902 40902 11.09 466.91 40964 40964 40964 11.24 472.36 41025 41025 41025 11.25 477.11 41087 41087 41087 11.35 478.63 41210 41210 41210 11.21 471.04 41271 41271 41271 11.14 470.4 41333 41333 41333 11.02 468.0 41394 41394 41394 11.03 465.13 41456 41456 41456 11.06 468.49 41517 41517 41517 11.06 463.41 41579 41579 41579 10.92 462.34 41640 41640 41640 10.99 466.12 41702 41702 41702 10.94 466.13 41825 41825 41825 11.09 465.31 41886 41886 41886 10.91 467.4 41948 41948 41948 10.97 467.66 42009 42009 42009 10.91 467.11 42071 42071 42071 11.07 465.19 42132 42132 42132 11.11 463.46 42194 42194 42194 11.14 464.37 42255 42255 42255 11.14 465.33 42317 42317 42317 11.11 466.95 42440 42440 42440 11.18 467.82 42501 42501 42501 11.22 471.34 42563 42563 42563 11.22 472.22 42624 42624 42624 11.15 473.03 42686 42686 42686 11.37 481.72 42747 42747 42747 11.29 476.69 42809 42809 42809 11.19 475.08 42870 42870 42870 11.14 471.91 42932 42932 42932 11.12 469.19 43055 43055 43055 11.12 474.6 43116 43116 43116 11.07 471.33 43178 43178 43178 11.06 468.54 43239 43239 43239 11.11 472.79 43301 43301 43301 11.22 469.65 43362 43362 43362 11.24 477.7 43424 43424 43424 11.17 473.75 43485 43485 43485 11.16 471.77 43547 43547 43547 11.02 471.0 43670 43670 43670 11.04 471.9 43731 43731 43731 10.9 461.41 43793 43793 43793 10.84 458.94 43854 43854 43854 10.95 463.5 43916 43916 43916 11.1 466.87 43977 43977 43977 10.97 463.91 44039 44039 44039 11.03 463.73 44100 44100 44100 10.98 463.1 44162 44162 44162 10.98 457.38 44285 44285 44285 11.33 481.52 44346 44346 44346 11.19 480.74 44408 44408 44408 11.36 481.05 44469 44469 44469 11.34 479.16 44531 44531 44531 11.27 475.5 44592 44592 44592 11.36 479.07 44654 44654 44654 11.24 475.99 44715 44715 44715 11.35 478.53 44777 44777 44777 11.37 477.65 44900 44900 44900 11.27 472.37 44961 44961 44961 11.1 466.69 45023 45023 45023 11.11 469.42 45084 45084 45084 11.14 469.26 45146 45146 45146 11.01 467.19 45207 45207 45207 11.22 469.34 45269 45269 45269 11.16 468.38 45330 45330 45330 11.06 465.48 45392 45392 45392 11.19 468.24 45515 45515 45515 11.13 466.85 45576 45576 45576 11.11 466.46 45638 45638 45638 11.15 466.87 45699 45699 45699 11.11 465.85 45761 45761 45761 11.12 463.55 45822 45822 45822 11.1 461.59 45884 45884 45884 10.98 466.23 45945 45945 45945 11.08 467.06 46007 46007 46007 11.21 468.92 46130 46130 46130 11.06 468.33 46191 46191 46191 11.06 464.95 46253 46253 46253 11.13 468.19 46314 46314 46314 10.95 466.25 46376 46376 46376 10.99 462.93 46437 46437 46437 11.04 463.14 46499 46499 46499 11.03 463.58 46560 46560 46560 10.94 466.1 46622 46622 46622 10.92 466.75 46745 46745 46745 11.02 468.33 46806 46806 46806 11.11 468.31 46868 46868 46868 11.06 466.6 46929 46929 46929 11.08 466.68 46991 46991 46991 11.02 467.66 47052 47052 47052 11.07 468.0 47114 47114 47114 11.32 471.0 47175 47175 47175 11.25 471.88 47237 47237 47237 11.2 477.0 47360 47360 47360 11.3 477.18 47421 47421 47421 11.27 478.57 47483 47483 47483 11.14 477.3 47544 47544 47544 11.3 479.34 47606 47606 47606 11.18 478.21 47667 47667 47667 11.17 477.78 47729 47729 47729 11.1 478.75 47790 47790 47790 10.97 477.31 47852 47852 47852 11.06 477.39 47975 47975 47975 11.1 478.58 48036 48036 48036 11.2 477.4 48098 48098 48098 11.17 476.93 48159 48159 48159 11.19 478.51 48221 48221 48221 11.21 477.65 48282 48282 48282 11.19 477.39 48344 48344 48344 11.41 478.48 48405 48405 48405 11.34 477.65 48467 48467 48467 11.29 478.34 48590 48590 48590 11.32 479.24 48651 48651 48651 11.23 478.33 48713 48713 48713 11.33 478.87 48774 48774 48774 11.49 478.96 48836 48836 48836 11.28 478.88 48897 48897 48897 11.35 478.33 48959 48959 48959 11.35 478.14 49021 49021 49021 11.43 477.2 49082 49082 49082 11.4 478.62 49205 49205 49205 11.42 479.39 49267 49267 49267 11.32 478.3 49328 49328 49328 11.43 478.91 49390 49390 49390 11.27 478.12 49451 49451 49451 11.43 479.29 49513 49513 49513 11.3 479.96 49574 49574 49574 11.29 479.91 49636 49636 49636 11.36 478.93 49697 49697 49697 11.43 478.9 49820 49820 49820 11.42 481.19 49882 49882 49882 11.32 482.18 49943 49943 49943 11.18 481.28 50005 50005 50005 11.48 479.53 50066 50066 50066 11.36 480.55 50128 50128 50128 11.31 478.82 50189 50189 50189 11.29 480.06 50251 50251 50251 11.42 480.53 50312 50312 50312 11.29 477.99 50435 50435 50435 11.37 478.3 50497 50497 50497 11.39 475.34 50558 50558 50558 11.34 473.99 50620 50620 50620 11.3 475.15 50681 50681 50681 11.28 473.07 50743 50743 50743 11.17 472.33 50804 50804 50804 11.29 472.14 50866 50866 50866 11.3 471.35 50927 50927 50927 11.21 471.52 51050 51050 51050 11.24 466.47 51112 51112 51112 11.18 467.28 51173 51173 51173 11.1 467.78 51235 51235 51235 11.2 467.14 51296 51296 51296 11.24 471.71 51358 51358 51358 11.22 472.35 51419 51419 51419 11.25 471.94 51481 51481 51481 11.21 471.95 51542 51542 51542 11.12 472.33 51665 51665 51665 11.14 472.12 51727 51727 51727 11.24 472.23 51788 51788 51788 11.14 471.19 51850 51850 51850 11.12 472.2 51911 51911 51911 11.22 471.3 51973 51973 51973 11.12 470.58 52034 52034 52034 11.02 473.03 52096 52096 52096 11.14 472.77 52157 52157 52157 11.2 472.86 52280 52280 52280 11.2 471.7 52342 52342 52342 11.16 473.19 52403 52403 52403 11.19 471.14 52465 52465 52465 11.09 470.76 52526 52526 52526 11.13 472.71 52588 52588 52588 11.03 473.81 52649 52649 52649 11.15 472.25 52711 52711 52711 11.02 473.67 52772 52772 52772 11.18 474.5 52895 52895 52895 11.18 474.51 52957 52957 52957 11.29 475.12 53018 53018 53018 11.04 471.84 53080 53080 53080 11.09 467.57 53141 53141 53141 11.03 467.45 53203 53203 53203 11.2 467.73 53264 53264 53264 11.03 467.12 53326 53326 53326 11.19 466.94 53387 53387 53387 11.24 467.69 53510 53510 53510 11.03 469.08 53572 53572 53572 11.01 467.56 53633 53633 53633 11.15 471.34 53695 53695 53695 11.3 471.1 53756 53756 53756 11.22 473.0 53818 53818 53818 11.17 471.08 53879 53879 53879 11.17 473.46 53941 53941 53941 11.35 472.77 54002 54002 54002 11.19 474.42 54125 54125 54125 11.29 472.92 54187 54187 54187 11.2 472.64 54248 54248 54248 11.12 472.75 54310 54310 54310 11.27 473.48 54371 54371 54371 11.2 473.67 54433 54433 54433 11.18 473.66 54494 54494 54494 11.13 474.93 54556 54556 54556 11.25 474.36 54617 54617 54617 11.18 472.37 54740 54740 54740 11.22 472.7 54802 54802 54802 11.24 472.84 54863 54863 54863 11.16 474.89 54925 54925 54925 11.2 473.67 54986 54986 54986 11.12 472.85 55048 55048 55048 11.08 474.59 55109 55109 55109 11.17 473.45 55171 55171 55171 11.12 475.85 55232 55232 55232 11.37 477.26 55355 55355 55355 11.24 475.8 55417 55417 55417 11.2 478.54 55478 55478 55478 11.08 474.79 55540 55540 55540 11.16 476.32 55601 55601 55601 10.97 473.84 55663 55663 55663 11.29 483.23 55724 55724 55724 11.4 484.88 55786 55786 55786 11.49 481.9 55847 55847 55847 11.74 489.94 55970 55970 55970 11.5 489.29 56032 56032 56032 11.7 489.06 56093 56093 56093 11.66 489.22 56155 56155 56155 11.71 489.13 56216 56216 56216 11.74 487.97 56278 56278 56278 11.45 489.2 56339 56339 56339 11.56 488.67 56401 56401 56401 11.65 489.11 56462 56462 56462 11.61 488.49 56585 56585 56585 11.59 488.88 56647 56647 56647 11.53 487.69 56708 56708 56708 11.6 487.4 56770 56770 56770 11.51 487.43 56831 56831 56831 11.47 487.8 56893 56893 56893 11.6 487.63 56954 56954 56954 11.54 489.05 57016 57016 57016 11.56 489.87 57077 57077 57077 11.39 490.39 57200 57200 57200 11.46 488.67 57262 57262 57262 11.36 486.02 57323 57323 57323 11.46 486.26 57385 57385 57385 11.7 485.72 57447 57447 57447 11.5 487.07 57508 57508 57508 11.54 485.72 57570 57570 57570 11.45 481.28 57631 57631 57631 11.66 485.07 57693 57693 57693 11.7 486.17 57816 57816 57816 12.04 486.5 57877 57877 57877 11.84 485.49 57939 57939 57939 11.87 486.69 58000 58000 58000 11.93 486.93 58062 58062 58062 11.9 486.13