63 1001 Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument WISE 1 1 2017 09 18 2018 03 14 0 Mean sample time in UT seconds past midnight of flight date 10 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 H1301 [ppt] H1211 [ppt] H2402 [ppt] H1202 [ppt] CH3Br [ppt] CH2Br2 [ppt] CHBr3 [ppt] CH2BrCl [ppt] CHBrCl2 [ppt] CHBr2Cl [ppt] 37 ------------------------------------------------------------------------ WISE flight 03 on 18.09.2017 PRELIMINARY DATA ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the WISE data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: "TO-Mutter" (UEA scales), "AGAGE H-218" (all other scales) Calibration Scales SIO-05 SIO-05 SIO-14 UEA-09 SIO-05 NOAA-Jul10-p NOAA-Dec09-p SIO-10-p UEA-11 UEA-11 ------------------------------------------------------------------------ CH3Br derived from H1211 using correlation based on balloon measurements in 2009 and 2011. CH2Br2 and CHBr2Cl derived using correlation from HALO PGS campaign 2015/2016 ------------------------------------------------------------------------ Instrument precision in [%] 0.99 0.49 1.49 7.58 4.22 0.67 2.21 9.16 3.43 2.22 Instrument precision in [ppt] 0.039 0.046 0.005 0.001 0.333 0.012 0.015 0.025 0.002 0.004 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] 0.6 0.3 0.8 25.0 NaN 4.9 17.3 5.8 20.6 6.3 ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP 0.050 0.006 0.007 0.006 0.646 0.011 0.086 0.130 0.002 0.002 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 54 +- 1 seconds Values of t_sample are the mean of the sampling time interval ("integration time") ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): all substances Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 UTC H1301 H1211 H2402 H1202 CH3Br CH2Br2 CHBr3 CH2BrCl CHBrCl2 CHBr2Cl [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] 29659 3.424 3.473 0.396 0.010 8.423 0.942 1.416 0.263 0.177 0.141 29908 3.485 3.443 0.399 99999 8.354 1.097 1.900 0.231 0.206 0.217 30406 3.182 3.056 0.359 0.012 7.480 0.496 0.140 99999 0.093 0.046 30655 3.294 3.107 0.361 0.007 7.591 0.521 0.161 0.182 0.097 0.050 30902 3.218 3.148 0.364 0.014 7.684 0.515 0.137 0.156 0.096 0.049 31150 3.299 3.197 0.376 0.012 7.793 0.551 0.201 0.139 0.103 0.054 31399 3.383 3.245 0.396 0.014 7.901 0.580 0.214 0.208 0.108 0.066 31646 3.260 3.293 0.385 0.015 8.009 0.594 0.247 99999 0.111 0.065 31894 3.218 3.257 0.377 0.019 7.929 0.586 0.185 99999 0.109 0.065 32142 3.317 3.174 0.380 0.015 7.741 0.543 0.164 0.187 0.101 0.056 32390 3.231 3.173 0.381 0.011 7.740 0.511 0.165 0.169 0.095 0.047 32886 3.393 3.342 0.391 0.014 8.122 0.744 0.540 0.236 0.139 0.099 33133 3.344 3.386 0.397 0.016 8.221 0.771 0.614 99999 0.144 0.109 33382 3.432 3.439 0.395 0.009 8.344 0.780 0.637 99999 0.146 0.110 33629 3.364 3.381 0.399 0.019 8.212 0.777 0.626 0.199 0.145 0.116 33876 3.341 3.337 0.388 0.021 8.110 0.691 0.451 0.182 0.129 0.098 34125 3.383 3.273 0.370 0.016 7.963 0.677 0.404 0.180 0.127 0.102 34374 3.406 3.388 0.394 0.013 8.227 0.686 0.507 99999 0.128 0.092 34621 3.259 3.130 0.374 0.010 7.643 0.493 0.125 0.142 0.092 0.055 34868 3.234 3.159 0.362 0.017 7.708 0.502 0.135 99999 0.094 0.049 35364 3.340 3.325 0.373 0.014 8.084 0.677 0.282 99999 0.127 0.099 35614 3.376 3.355 0.380 0.015 8.152 0.667 0.312 99999 0.125 0.088 35864 3.380 3.338 0.384 0.013 8.113 0.677 0.248 99999 0.127 0.105 36113 3.408 3.413 0.398 0.015 8.285 0.700 0.379 0.242 0.131 0.102 36363 3.443 3.456 0.389 99999 8.385 0.738 0.345 99999 0.138 0.121 36613 3.411 3.391 0.396 0.012 8.233 0.718 0.339 0.210 0.134 0.112 36863 3.437 3.405 0.385 0.012 8.266 0.696 0.289 99999 0.130 0.115 37113 3.467 3.366 0.401 0.015 8.176 0.695 0.327 99999 0.130 0.101 37362 3.474 3.437 0.404 0.013 8.341 0.663 0.343 0.228 0.124 0.108 37860 3.383 3.421 0.404 0.015 8.304 0.682 0.321 99999 0.128 0.096 38110 3.356 3.429 0.396 0.011 8.321 0.707 0.351 0.225 0.132 0.107 38360 3.392 3.447 0.397 0.012 8.363 0.690 0.350 0.194 0.129 0.100 38610 3.378 3.438 0.407 0.012 8.344 0.717 0.449 0.187 0.134 0.125 38860 3.324 3.402 0.403 0.015 8.259 0.707 0.335 0.191 0.132 0.085 39109 3.333 3.470 0.392 0.015 8.417 0.673 0.330 99999 0.126 0.087 39359 3.297 3.427 0.392 0.011 8.316 0.702 0.393 99999 0.131 0.099 39609 3.339 3.414 0.402 0.013 8.287 0.734 0.569 99999 0.138 0.104 39859 3.353 3.391 0.394 0.013 8.234 0.774 0.568 99999 0.145 0.107 40108 3.291 3.458 0.401 99999 8.388 0.707 0.343 0.201 0.132 0.076 40356 3.368 3.439 0.398 0.014 8.345 0.708 0.201 0.198 0.132 0.068 40604 3.313 3.384 0.404 0.014 8.217 0.686 0.204 0.198 0.128 0.070 41101 3.289 3.421 0.388 0.016 8.303 0.684 0.204 0.171 0.128 0.074 41350 3.297 3.366 0.389 0.014 8.177 0.673 0.219 0.187 0.126 0.078 41599 3.222 3.289 0.391 0.013 8.002 0.609 0.174 0.170 0.114 0.065 41847 3.322 3.227 0.382 0.011 7.860 0.602 0.131 0.186 0.112 0.065 42096 3.179 3.191 0.384 0.016 7.779 0.590 0.126 0.239 0.110 0.055 42344 3.326 3.171 0.371 0.012 7.735 0.550 0.115 0.201 0.103 0.054 42841 3.404 3.219 0.369 0.014 7.843 0.550 0.076 0.183 0.103 0.054 43089 3.292 3.271 0.376 0.014 7.960 0.592 0.100 0.228 0.111 0.050 43337 3.315 3.267 0.366 0.011 7.952 0.550 0.106 0.205 0.103 0.058 43585 3.214 3.279 0.382 0.012 7.979 0.594 0.103 0.215 0.111 0.062 43835 3.271 3.295 0.372 0.013 8.014 0.565 0.090 0.236 0.105 0.052 44083 3.344 3.354 0.394 0.012 8.149 0.593 0.105 0.213 0.111 0.059 44332 3.223 3.256 0.363 0.013 7.925 0.535 0.079 99999 0.100 0.055 44580 3.232 3.140 0.375 0.011 7.666 0.478 0.081 0.179 0.089 0.038 44828 3.293 3.224 0.373 0.010 7.853 0.542 0.077 0.184 0.101 0.054 45077 3.207 2.991 0.345 0.013 7.336 0.415 0.075 0.208 0.077 0.038 45575 3.160 3.068 0.349 0.014 7.506 0.409 0.059 0.166 0.076 0.046 45823 3.247 3.148 0.356 0.011 7.684 0.468 0.094 0.206 0.087 0.056 46072 3.207 3.070 0.351 0.010 7.510 0.426 0.077 99999 0.079 0.041 46320 3.283 3.116 0.375 0.012 7.612 0.484 0.095 99999 0.090 0.043 46568 3.290 3.112 0.365 0.012 7.604 0.490 0.088 99999 0.091 0.042 46816 3.268 3.128 0.360 0.013 7.638 0.465 0.067 0.184 0.087 0.051 47064 3.220 3.175 0.357 0.010 7.744 0.505 0.000 99999 0.094 0.045 47312 3.290 3.072 0.364 0.012 7.515 0.434 0.083 99999 0.081 0.045 47807 3.228 3.030 0.360 0.011 7.423 0.416 0.063 99999 0.077 0.040 48055 3.286 3.130 0.359 0.012 7.643 0.475 0.105 0.164 0.089 0.044 48303 3.250 3.065 0.353 0.009 7.498 0.410 0.000 0.136 0.076 0.046 48551 3.283 3.070 0.350 0.015 7.509 0.419 0.087 0.144 0.078 0.040 48799 3.255 3.184 0.381 0.012 7.765 0.468 0.090 99999 0.087 0.051 49047 3.336 3.119 0.376 0.019 7.618 0.423 0.000 0.185 0.079 0.040 49295 3.350 3.142 0.364 0.016 7.669 0.450 0.083 99999 0.084 0.044 49543 3.300 3.214 0.374 0.013 7.831 0.495 0.086 0.159 0.092 0.051 49791 3.366 3.263 0.374 0.016 7.942 0.505 0.082 0.118 0.094 0.052 50287 3.236 3.111 0.361 0.011 7.602 0.410 0.053 99999 0.076 0.042 50535 3.274 3.072 0.364 0.015 7.514 0.442 0.068 0.141 0.082 0.038 50783 3.159 2.914 0.340 0.012 7.170 0.334 0.060 0.124 0.062 0.027 51032 3.173 2.969 0.348 0.016 7.290 0.345 0.000 0.144 0.064 0.029 51280 3.198 3.012 0.344 0.013 7.384 0.363 0.000 99999 0.067 0.034 51529 3.194 3.007 0.356 0.014 7.373 0.380 0.000 0.178 0.070 0.034 51777 3.195 3.017 0.362 0.020 7.393 0.364 0.000 99999 0.067 0.033 52026 3.158 3.052 0.366 0.016 7.472 0.385 0.000 99999 0.071 0.030 52274 3.212 3.198 0.389 0.018 7.794 0.455 0.069 99999 0.085 0.039 52770 3.173 3.082 0.364 0.017 7.536 0.402 0.074 0.155 0.075 0.045 53018 3.208 3.028 0.349 0.013 7.418 0.374 0.078 99999 0.069 0.039 53267 3.196 3.063 0.369 0.009 7.495 0.384 0.104 0.150 0.071 0.042 53515 3.197 3.034 0.361 0.012 7.431 0.379 0.066 0.135 0.070 0.036 53763 3.363 3.291 0.382 0.019 8.005 0.531 0.113 0.128 0.099 0.051 54013 3.366 3.260 0.381 0.015 7.935 0.503 0.086 0.195 0.094 0.050 54261 3.313 3.325 0.392 0.014 8.083 0.546 0.104 0.218 0.102 0.049 54511 3.329 3.345 0.377 0.017 8.129 0.560 0.097 0.170 0.105 0.050 54759 3.350 3.293 0.385 0.014 8.010 0.530 0.082 99999 0.099 0.040 55256 3.314 3.315 0.379 0.016 8.060 0.510 0.098 0.160 0.095 0.046 55505 3.345 3.349 0.374 0.014 8.138 0.595 0.122 99999 0.111 0.063 55754 3.419 3.320 0.386 0.015 8.071 0.527 0.102 99999 0.098 0.045 56003 3.342 3.335 0.384 0.016 8.107 0.583 0.120 99999 0.109 0.060 56251 3.375 3.383 0.385 0.015 8.215 0.565 0.113 99999 0.106 0.050 56501 3.319 3.378 0.379 0.015 8.204 0.582 0.107 0.183 0.109 0.054 56750 3.429 3.423 0.380 0.015 8.307 0.583 0.108 99999 0.109 0.059 57000 3.358 3.388 0.384 0.018 8.227 0.583 0.091 0.181 0.109 0.044 57248 3.312 3.346 0.377 0.017 8.130 0.561 0.079 99999 0.105 0.056 57745 3.382 3.418 0.379 0.018 8.296 0.572 0.089 99999 0.107 0.052 57994 3.365 3.344 0.388 0.018 8.127 0.558 0.099 99999 0.104 0.044 58244 3.379 3.357 0.391 0.017 8.157 0.579 0.106 99999 0.108 0.054 58493 3.388 3.360 0.380 0.012 8.163 0.559 0.085 0.136 0.104 0.050 58743 3.376 3.374 0.383 0.022 8.195 0.577 0.089 0.185 0.108 0.046 58992 3.317 3.296 0.374 0.020 8.017 0.528 0.096 99999 0.098 0.051 59240 3.381 3.285 0.382 0.018 7.992 0.575 0.109 0.150 0.107 0.052 59738 3.380 3.248 0.379 0.020 7.908 0.531 0.079 99999 0.099 0.043 59986 3.261 3.135 0.353 0.015 7.654 0.452 0.087 0.172 0.084 0.034 60236 3.257 3.149 0.365 0.012 7.685 0.441 0.061 0.092 0.082 0.033 60485 3.188 3.139 0.372 0.015 7.663 0.483 0.089 0.188 0.090 0.035 60983 3.320 3.333 0.396 0.014 8.101 0.609 0.165 99999 0.114 0.068 61232 3.376 3.484 0.410 0.014 8.450 0.730 0.384 99999 0.137 0.117 61481 3.379 3.476 0.393 0.012 8.432 0.714 0.303 99999 0.134 0.109 61730 3.325 3.375 0.386 0.014 8.197 0.789 0.679 99999 0.148 0.126 61981 3.341 3.462 0.407 0.014 8.399 0.895 1.151 0.160 0.168 0.158 62230 3.337 3.447 0.394 0.012 8.365 1.126 1.989 99999 0.211 0.219 62480 3.504 3.500 0.404 0.018 8.486 1.432 3.384 0.269 0.269 0.334 62730 3.361 3.449 0.395 0.014 8.369 1.426 3.055 0.242 0.268 0.375