63 1001 Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument WISE 1 1 2017 10 07 2018 03 14 0 Mean sample time in UT seconds past midnight of flight date 10 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 H1301 [ppt] H1211 [ppt] H2402 [ppt] H1202 [ppt] CH3Br [ppt] CH2Br2 [ppt] CHBr3 [ppt] CH2BrCl [ppt] CHBrCl2 [ppt] CHBr2Cl [ppt] 37 ------------------------------------------------------------------------ WISE flight 10 on 07.10.2017 PRELIMINARY DATA ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the WISE data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: "TO-Mutter" (UEA scales), "AGAGE H-218" (all other scales) Calibration Scales SIO-05 SIO-05 SIO-14 UEA-09 SIO-05 NOAA-Jul10-p NOAA-Dec09-p SIO-10-p UEA-11 UEA-11 ------------------------------------------------------------------------ CH3Br derived from H1211 using correlation based on balloon measurements in 2009 and 2011. CH2Br2 and CHBr2Cl derived using correlation from HALO PGS campaign 2015/2016 ------------------------------------------------------------------------ Instrument precision in [%] 0.99 0.49 1.49 7.58 4.22 0.67 2.21 9.16 3.43 2.22 Instrument precision in [ppt] 0.039 0.046 0.005 0.001 0.333 0.012 0.015 0.025 0.002 0.004 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] 0.6 0.3 0.8 25.0 NaN 4.9 17.3 5.8 20.6 6.3 ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP 0.050 0.006 0.007 0.006 0.646 0.011 0.086 0.130 0.002 0.002 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 54 +- 1 seconds Values of t_sample are the mean of the sampling time interval ("integration time") ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): all substances Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 UTC H1301 H1211 H2402 H1202 CH3Br CH2Br2 CHBr3 CH2BrCl CHBrCl2 CHBr2Cl [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] 45457 3.175 3.170 0.389 0.016 7.733 1.496 3.040 99999 0.281 0.336 45708 99999 3.237 0.399 0.017 7.883 1.503 3.163 99999 0.283 0.325 45972 3.212 3.095 0.398 99999 7.566 1.088 1.552 0.153 0.204 0.199 46228 3.215 3.128 0.379 0.015 7.640 0.794 0.520 99999 0.149 0.114 46489 3.289 3.194 0.387 0.016 7.785 0.782 0.448 99999 0.147 0.115 47010 3.211 3.177 0.386 0.012 7.748 0.848 0.580 0.238 0.159 0.141 47279 3.273 3.258 0.395 0.013 7.931 0.773 0.396 99999 0.145 0.115 47532 3.231 3.263 0.381 0.012 7.941 0.702 0.206 99999 0.131 0.111 48279 3.261 3.214 0.388 0.015 7.830 1.083 0.658 99999 0.203 0.350 48527 3.264 3.118 0.382 0.014 7.617 0.741 0.297 99999 0.139 0.132 48776 3.199 3.091 0.361 0.012 7.557 0.667 0.208 99999 0.125 0.089 49023 3.260 3.116 0.361 0.020 7.611 0.637 0.178 99999 0.119 0.086 49270 3.278 3.093 0.358 99999 7.561 0.633 0.142 99999 0.118 0.071 49518 99999 3.066 0.364 0.014 7.502 0.654 0.167 99999 0.122 0.077 50016 3.412 3.258 0.391 0.017 7.931 0.784 0.233 99999 0.147 0.101 50263 3.326 3.188 0.384 0.016 7.772 0.682 0.197 0.252 0.128 0.078 50510 3.275 3.167 0.374 0.013 7.726 0.646 0.140 99999 0.121 0.067 50758 3.337 3.198 0.374 0.015 7.795 0.691 0.188 99999 0.129 0.077 51005 3.320 3.162 0.386 0.015 7.713 0.658 0.164 0.206 0.123 0.071 51253 3.319 3.203 0.387 0.013 7.807 0.703 0.213 99999 0.132 0.078 51500 3.291 3.159 0.384 0.014 7.707 0.727 0.226 99999 0.136 0.083 51998 3.369 3.134 0.380 0.015 7.652 0.736 0.252 99999 0.138 0.087 52245 3.360 3.088 0.387 0.016 7.550 0.741 0.274 99999 0.139 0.082 52492 3.374 3.196 0.396 0.011 7.791 0.731 0.247 0.161 0.137 0.090 52740 3.307 3.164 0.383 0.014 7.719 0.720 0.248 99999 0.135 0.082 52987 3.290 3.114 0.379 0.011 7.607 0.662 0.171 99999 0.124 0.067 53234 3.290 3.145 0.376 0.013 7.676 0.697 0.192 99999 0.131 0.072 53481 3.289 3.074 0.392 0.013 7.519 0.704 0.224 99999 0.132 0.083 53729 3.390 3.185 0.388 0.015 7.765 0.729 0.235 0.189 0.136 0.090 53976 3.358 3.208 0.388 99999 7.817 0.734 0.211 0.214 0.137 0.084 54473 3.302 3.173 0.388 0.013 7.739 0.722 0.173 99999 0.135 0.085 54721 3.332 3.122 0.392 0.014 7.625 0.706 0.199 99999 0.132 0.078 54968 3.392 3.240 0.390 0.016 7.891 0.678 0.136 0.177 0.127 0.070 55214 3.256 3.157 0.394 0.017 7.704 0.676 0.160 99999 0.126 0.073 55462 3.250 3.122 0.370 0.014 7.624 0.580 0.105 0.133 0.108 0.057 55709 3.128 2.999 0.371 0.014 7.353 0.540 0.076 99999 0.101 0.050 55956 3.242 3.175 0.368 0.012 7.745 0.596 0.112 99999 0.111 0.062 56204 3.215 3.168 0.379 0.014 7.728 0.589 0.115 0.157 0.110 0.059 56452 3.229 3.144 0.380 0.015 7.674 0.607 0.114 0.181 0.114 0.061 56947 3.289 3.276 0.393 0.015 7.972 0.720 0.162 99999 0.135 0.081 57194 3.209 3.237 0.381 0.014 7.883 0.662 0.138 99999 0.124 0.074 57442 3.334 3.179 0.383 0.014 7.752 0.654 0.135 0.170 0.122 0.062 57688 3.190 3.155 0.376 0.014 7.699 0.611 0.121 99999 0.114 0.062 57935 3.288 3.172 0.377 0.016 7.736 0.585 0.097 99999 0.109 0.050 58182 3.317 3.129 0.381 0.015 7.642 0.612 0.111 0.194 0.114 0.062 58429 3.334 3.275 0.390 0.012 7.970 0.633 0.128 99999 0.118 0.062 58677 3.306 3.255 0.397 0.017 7.923 0.649 0.140 99999 0.121 0.065 58924 3.358 3.205 0.381 0.017 7.810 0.610 0.109 0.204 0.114 0.056 59421 3.385 3.207 0.388 0.015 7.815 0.613 0.110 99999 0.114 0.062 59669 3.291 3.184 0.387 0.012 7.763 0.585 0.088 99999 0.109 0.056 59916 3.360 3.280 0.383 0.014 7.980 0.641 0.122 0.194 0.120 0.057 60163 3.298 3.016 0.379 0.014 7.391 0.531 0.089 99999 0.099 0.046 61104 3.132 3.031 0.361 0.013 7.425 0.471 0.076 99999 0.088 0.046 61351 3.156 3.007 0.363 0.013 7.373 0.447 0.045 0.136 0.083 0.033 61600 3.180 3.034 0.353 0.013 7.430 0.444 0.047 99999 0.083 0.037 61847 3.293 3.194 0.386 0.014 7.785 0.523 0.074 99999 0.097 0.046 62328 3.495 3.371 0.414 0.018 8.187 0.703 0.101 0.144 0.132 0.065 62577 3.353 3.149 0.385 0.017 7.685 0.558 0.096 99999 0.104 0.047 62826 3.304 3.200 0.373 0.014 7.800 0.557 0.086 99999 0.104 0.049 63073 3.272 3.166 0.385 0.015 7.724 0.599 0.078 99999 0.112 0.048 63320 3.354 3.244 0.395 0.016 7.899 0.627 0.094 99999 0.117 0.062 63567 3.255 3.196 0.378 0.014 7.791 0.624 0.113 99999 0.117 0.060 63814 3.315 3.196 0.382 0.018 7.791 0.604 0.107 99999 0.113 0.060 64062 3.391 3.286 0.381 0.013 7.993 0.633 0.117 99999 0.118 0.068 64557 3.383 3.319 0.395 0.013 8.068 0.651 0.119 0.167 0.122 0.068 64804 3.289 3.331 0.391 0.014 8.096 0.671 0.151 0.198 0.126 0.073 65051 3.312 3.326 0.392 0.013 8.086 0.671 0.145 99999 0.126 0.064 65298 3.306 3.315 0.386 0.015 8.061 0.653 0.137 99999 0.122 0.071 65544 3.252 3.286 0.390 0.017 7.993 0.647 0.120 0.092 0.121 0.062 65790 3.288 3.283 0.384 0.013 7.988 0.659 0.135 99999 0.123 0.066 66037 3.200 3.219 0.378 0.013 7.841 0.597 0.109 99999 0.111 0.053 66284 3.230 3.214 0.382 0.015 7.830 0.614 0.129 99999 0.115 0.065 66531 3.095 3.030 0.364 0.012 7.423 0.489 0.080 99999 0.091 0.044 67027 3.124 2.932 0.345 0.012 7.208 0.470 0.065 99999 0.088 0.041 67273 3.036 2.916 0.341 0.015 7.175 0.437 0.052 0.151 0.081 0.032 67519 3.206 3.101 0.358 0.014 7.579 0.541 0.094 99999 0.101 0.050 67766 3.147 3.051 0.363 0.014 7.467 0.559 0.092 99999 0.104 0.055 68012 3.237 3.130 0.384 0.013 7.642 0.592 0.097 0.180 0.111 0.049 68258 3.180 3.265 0.382 0.014 7.947 0.651 0.135 0.206 0.122 0.068 68505 3.247 3.272 0.377 0.014 7.963 0.609 0.123 99999 0.114 0.062 68751 3.198 3.196 0.369 0.014 7.790 0.598 0.131 99999 0.112 0.061 69000 3.103 3.064 0.347 0.014 7.497 0.479 0.064 99999 0.089 0.044 69498 3.198 3.136 0.358 0.013 7.657 0.523 0.061 99999 0.098 0.043 69747 3.234 3.121 0.363 0.014 7.624 0.530 0.086 0.186 0.099 0.050 69995 3.192 3.027 0.361 0.012 7.415 0.521 0.083 0.162 0.097 0.047 70243 3.163 3.072 0.350 0.013 7.514 0.503 0.087 99999 0.094 0.048 70492 3.222 2.932 0.346 0.013 7.209 0.456 0.066 99999 0.085 0.035 70741 3.130 2.987 0.344 0.013 7.329 0.420 0.046 0.164 0.078 0.029 70989 3.157 2.957 0.349 0.010 7.263 0.417 0.032 99999 0.078 0.030 71238 3.159 2.974 0.345 0.010 7.300 0.425 0.000 99999 0.079 0.032 71486 3.188 2.934 0.341 99999 7.214 0.423 0.000 99999 0.079 0.027 72217 3.424 3.352 0.399 0.013 8.145 0.760 0.418 99999 0.142 0.122 72465 3.497 3.347 0.400 0.013 8.132 0.768 0.325 0.126 0.144 0.099 72713 3.365 3.400 0.393 0.014 8.256 0.751 0.462 99999 0.141 0.111 72960 3.365 3.312 0.401 0.013 8.054 0.726 0.405 0.163 0.136 0.100 73208 3.276 3.375 0.384 0.015 8.198 0.876 0.601 99999 0.164 0.178 73455 3.276 3.379 0.394 0.016 8.206 0.819 0.547 99999 0.154 0.135 73703 3.401 3.485 0.422 0.018 8.453 1.313 2.042 99999 0.247 0.307