63 1001 Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument WISE 1 1 2017 10 09 2018 03 14 0 Mean sample time in UT seconds past midnight of flight date 10 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 H1301 [ppt] H1211 [ppt] H2402 [ppt] H1202 [ppt] CH3Br [ppt] CH2Br2 [ppt] CHBr3 [ppt] CH2BrCl [ppt] CHBrCl2 [ppt] CHBr2Cl [ppt] 37 ------------------------------------------------------------------------ WISE flight 11 on 09.10.2017 PRELIMINARY DATA ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the WISE data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: "TO-Mutter" (UEA scales), "AGAGE H-218" (all other scales) Calibration Scales SIO-05 SIO-05 SIO-14 UEA-09 SIO-05 NOAA-Jul10-p NOAA-Dec09-p SIO-10-p UEA-11 UEA-11 ------------------------------------------------------------------------ CH3Br derived from H1211 using correlation based on balloon measurements in 2009 and 2011. CH2Br2 and CHBr2Cl derived using correlation from HALO PGS campaign 2015/2016 ------------------------------------------------------------------------ Instrument precision in [%] 0.99 0.49 1.49 7.58 4.22 0.67 2.21 9.16 3.43 2.22 Instrument precision in [ppt] 0.039 0.046 0.005 0.001 0.333 0.012 0.015 0.025 0.002 0.004 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] 0.6 0.3 0.8 25.0 NaN 4.9 17.3 5.8 20.6 6.3 ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP 0.050 0.006 0.007 0.006 0.646 0.011 0.086 0.130 0.002 0.002 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 54 +- 1 seconds Values of t_sample are the mean of the sampling time interval ("integration time") ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): all substances Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 UTC H1301 H1211 H2402 H1202 CH3Br CH2Br2 CHBr3 CH2BrCl CHBrCl2 CHBr2Cl [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] 35787 99999 3.338 0.402 0.015 8.112 0.737 0.247 0.348 0.138 0.091 36074 99999 3.359 0.392 0.013 8.161 0.713 0.178 99999 0.133 0.077 36360 3.396 3.344 0.384 0.012 8.125 0.668 0.171 99999 0.125 0.075 36645 99999 3.339 0.386 0.017 8.115 0.675 0.160 99999 0.126 0.070 36931 3.278 3.219 0.367 0.017 7.842 0.621 0.153 99999 0.116 0.069 37216 99999 3.165 0.373 0.016 7.721 0.580 0.114 99999 0.108 0.064 37499 3.216 3.143 0.374 0.017 7.671 0.562 0.112 99999 0.105 0.052 38032 99999 3.343 0.382 0.015 8.124 0.693 0.246 99999 0.130 0.087 38317 99999 3.303 0.381 0.019 8.033 0.708 0.256 0.110 0.132 0.083 38600 3.256 3.217 0.370 0.015 7.837 0.645 0.182 99999 0.121 0.074 38883 99999 3.074 0.354 0.013 7.519 0.512 0.095 0.174 0.095 0.055 39166 99999 3.081 0.355 0.013 7.534 0.527 0.084 0.000 0.098 0.049 39450 99999 3.059 0.352 0.013 7.487 0.509 0.074 0.187 0.095 0.048 39735 99999 3.031 0.356 0.014 7.424 0.542 0.096 99999 0.101 0.054 40023 3.178 3.070 0.349 0.015 7.510 0.522 0.000 99999 0.097 0.048 40312 99999 3.108 0.365 0.011 7.594 0.587 0.097 0.268 0.110 0.061 40852 99999 3.149 0.376 0.012 7.685 0.593 0.112 99999 0.111 0.066 41142 99999 3.302 0.393 0.013 8.031 0.730 0.215 99999 0.137 0.098 41431 99999 3.199 0.373 0.013 7.797 0.636 0.150 0.201 0.119 0.072 41720 99999 3.117 0.359 0.015 7.614 0.582 0.100 99999 0.109 0.055 42009 99999 2.951 0.349 0.013 7.250 0.468 0.037 0.155 0.087 0.044 42297 99999 2.982 0.342 0.011 7.317 0.477 0.000 99999 0.089 0.042 42578 3.187 3.090 0.354 0.015 7.555 0.526 0.000 99999 0.098 0.053 42842 3.413 3.314 0.391 0.015 8.058 0.650 0.127 99999 0.122 0.075 43092 3.357 3.294 0.375 0.017 8.013 0.636 0.160 0.235 0.119 0.068 43591 3.380 3.302 0.373 0.014 8.030 0.601 0.127 99999 0.112 0.061 43839 3.289 3.292 0.383 0.017 8.007 0.591 0.112 99999 0.110 0.060 44086 3.281 3.266 0.360 0.018 7.948 0.582 0.082 0.000 0.109 0.056 44334 3.232 3.234 0.357 0.017 7.876 0.571 0.070 99999 0.107 0.054 44582 3.239 3.278 0.373 0.018 7.976 0.572 0.119 0.131 0.107 0.062 44829 3.250 3.214 0.361 0.016 7.831 0.558 0.104 99999 0.104 0.055 45077 3.272 3.260 0.377 0.018 7.934 0.571 0.090 0.192 0.107 0.060 45326 3.270 3.155 0.357 0.015 7.699 0.504 0.102 0.234 0.094 0.047 45573 3.076 3.079 0.342 0.018 7.529 0.460 0.000 99999 0.086 0.034 46072 3.131 3.149 0.349 0.015 7.684 0.523 0.078 99999 0.098 0.050 46320 3.048 2.984 0.327 0.015 7.322 0.433 0.060 99999 0.081 0.037 46568 3.012 2.952 0.342 0.013 7.253 0.443 0.075 99999 0.082 0.045 46815 3.133 3.025 0.342 0.016 7.410 0.464 0.052 0.127 0.086 0.042 47062 3.084 2.983 0.330 0.013 7.319 0.445 0.000 99999 0.083 0.038 47309 3.047 2.913 0.325 0.011 7.168 0.402 0.000 0.117 0.075 0.033 47556 3.281 3.271 0.369 0.012 7.960 0.608 0.092 0.187 0.114 0.055 47803 3.282 3.205 0.356 0.013 7.811 0.557 0.081 99999 0.104 0.060 48050 3.329 3.318 0.387 0.013 8.067 0.649 0.166 99999 0.121 0.072 48547 3.375 3.364 0.396 0.015 8.172 0.671 0.149 99999 0.126 0.073 48794 3.342 3.321 0.395 0.014 8.074 0.674 0.185 99999 0.126 0.069 49040 3.128 2.908 0.334 0.010 7.156 0.387 0.000 0.180 0.072 0.033 49286 3.247 3.076 0.358 0.011 7.524 0.502 0.052 0.104 0.094 0.045 49533 3.190 3.011 0.356 0.013 7.381 0.476 0.089 0.188 0.089 0.046 49779 3.253 3.013 0.354 0.012 7.384 0.464 0.054 0.130 0.086 0.036 50025 3.173 3.015 0.345 0.011 7.389 0.434 0.043 99999 0.081 0.039 50272 3.122 2.915 0.347 0.011 7.171 0.420 0.000 0.151 0.078 0.033 50519 3.213 2.990 0.349 0.012 7.334 0.434 0.000 99999 0.081 0.030 51016 3.234 3.085 0.366 0.012 7.543 0.480 0.020 0.129 0.089 0.046 51263 3.222 3.090 0.361 0.011 7.555 0.488 0.089 99999 0.091 0.042 51510 3.141 2.821 0.330 0.011 6.971 0.359 0.000 99999 0.067 0.025 51756 3.376 3.178 0.373 0.015 7.750 0.594 0.089 99999 0.111 0.064 52002 3.310 3.148 0.361 0.012 7.682 0.534 0.074 0.131 0.100 0.051 52249 3.438 3.310 0.372 0.015 8.047 0.639 0.111 99999 0.119 0.060 52495 3.414 3.291 0.384 0.016 8.006 0.651 0.126 99999 0.122 0.065 52741 3.311 3.225 0.373 0.015 7.856 0.559 0.073 0.197 0.104 0.052 52990 3.217 2.917 0.329 0.013 7.177 0.412 0.045 0.182 0.077 0.032 53487 3.264 3.029 0.334 0.018 7.419 0.486 0.026 0.158 0.091 0.042 53734 3.237 2.939 0.328 0.011 7.224 0.432 0.074 99999 0.080 0.032 53980 3.140 2.935 0.340 0.014 7.215 0.445 0.049 99999 0.083 0.037 54227 3.056 2.852 0.305 0.014 7.035 0.390 0.000 0.103 0.072 0.023 54474 3.121 2.910 0.326 0.014 7.161 0.419 0.000 0.108 0.078 0.028 54721 3.031 2.810 0.305 0.013 6.946 0.374 0.000 0.110 0.069 0.025 54968 3.209 3.072 0.355 0.015 7.516 0.488 0.048 99999 0.091 0.032 55215 3.115 2.937 0.321 0.013 7.220 0.435 0.000 99999 0.081 0.038 55462 2.836 2.602 0.281 99999 6.511 0.301 0.000 0.115 0.056 0.021 55957 2.755 2.380 0.259 0.011 6.060 0.264 0.020 0.149 0.049 0.021 56204 2.839 2.488 0.269 0.011 6.277 0.295 0.000 99999 0.054 0.016 56450 2.761 2.396 0.269 0.013 6.093 0.268 0.000 99999 0.049 0.021 56698 2.764 2.384 0.262 0.010 6.067 0.262 0.000 0.165 0.048 0.020 56944 2.825 2.440 0.270 0.010 6.179 0.260 0.000 99999 0.048 0.025 57192 2.815 2.470 0.274 0.013 6.242 0.280 0.000 0.144 0.052 0.022 57439 2.798 2.470 0.274 0.012 6.241 0.275 0.000 99999 0.051 0.021 57687 2.752 2.341 0.256 0.007 5.981 0.250 0.000 0.180 0.046 0.018 57934 2.783 2.418 0.281 0.011 6.136 0.263 0.000 99999 0.048 0.019 58430 2.899 2.534 0.289 0.009 6.372 0.290 0.000 99999 0.053 0.023 58678 3.092 2.837 0.314 0.013 7.003 0.370 0.000 99999 0.069 0.030 58924 2.984 2.722 0.311 0.011 6.761 0.315 0.000 0.205 0.058 0.023 59171 3.230 3.172 0.354 0.011 7.736 0.489 0.000 99999 0.091 0.041 59419 3.119 2.858 0.318 0.012 7.049 0.363 0.000 0.134 0.067 0.026 59665 3.055 2.779 0.303 0.010 6.880 0.335 0.000 0.166 0.062 0.027 59912 3.168 2.947 0.324 0.012 7.241 0.398 0.047 99999 0.074 0.034 60159 3.242 3.210 0.360 0.012 7.823 0.507 0.000 99999 0.094 0.040 60408 3.356 3.368 0.378 0.012 8.180 0.671 0.181 0.158 0.126 0.081 60911 3.385 3.407 0.384 0.014 8.271 0.746 0.392 99999 0.140 0.115 61167 3.433 3.431 0.398 0.015 8.328 0.961 0.869 99999 0.180 0.172 61420 3.490 3.483 0.399 0.013 8.448 0.952 0.893 99999 0.179 0.194 61672 3.488 3.471 0.395 0.014 8.419 0.936 0.837 99999 0.176 0.184 61921 3.458 3.479 0.403 0.012 8.437 1.163 1.516 99999 0.219 0.279 62168 3.466 3.453 0.396 0.019 8.378 1.696 2.749 0.538 0.319 0.713 62415 3.363 3.465 0.402 0.016 8.405 1.298 2.188 0.382 0.244 0.259