63 1001 Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument WISE 1 1 2017 10 12 2018 03 14 0 Mean sample time in UT seconds past midnight of flight date 10 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 H1301 [ppt] H1211 [ppt] H2402 [ppt] H1202 [ppt] CH3Br [ppt] CH2Br2 [ppt] CHBr3 [ppt] CH2BrCl [ppt] CHBrCl2 [ppt] CHBr2Cl [ppt] 37 ------------------------------------------------------------------------ WISE flight 12 on 12.10.2017 PRELIMINARY DATA ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the WISE data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: "TO-Mutter" (UEA scales), "AGAGE H-218" (all other scales) Calibration Scales SIO-05 SIO-05 SIO-14 UEA-09 SIO-05 NOAA-Jul10-p NOAA-Dec09-p SIO-10-p UEA-11 UEA-11 ------------------------------------------------------------------------ CH3Br derived from H1211 using correlation based on balloon measurements in 2009 and 2011. CH2Br2 and CHBr2Cl derived using correlation from HALO PGS campaign 2015/2016 ------------------------------------------------------------------------ Instrument precision in [%] 0.99 0.49 1.49 7.58 4.22 0.67 2.21 9.16 3.43 2.22 Instrument precision in [ppt] 0.039 0.046 0.005 0.001 0.333 0.012 0.015 0.025 0.002 0.004 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] 0.6 0.3 0.8 25.0 NaN 4.9 17.3 5.8 20.6 6.3 ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP 0.050 0.006 0.007 0.006 0.646 0.011 0.086 0.130 0.002 0.002 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 54 +- 1 seconds Values of t_sample are the mean of the sampling time interval ("integration time") ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): all substances Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 UTC H1301 H1211 H2402 H1202 CH3Br CH2Br2 CHBr3 CH2BrCl CHBrCl2 CHBr2Cl [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] 35274 3.774 3.457 0.374 0.016 8.386 1.663 4.384 0.263 0.313 0.374 35524 3.335 3.375 0.385 0.015 8.196 1.551 3.578 99999 0.292 0.327 35774 3.264 3.459 0.380 0.020 8.391 1.609 3.860 99999 0.303 0.355 36025 3.296 3.386 0.394 0.018 8.223 1.410 3.354 99999 0.265 0.299 36528 3.287 3.427 0.381 0.019 8.317 0.795 99999 99999 0.149 0.114 36787 3.333 3.441 0.399 0.017 8.349 0.744 99999 99999 0.139 0.088 37049 3.264 3.422 0.392 0.015 8.307 0.792 99999 0.164 0.148 0.115 37315 3.345 3.452 0.401 0.017 8.376 0.826 0.440 99999 0.155 0.121 37587 3.318 3.419 0.391 0.015 8.299 0.863 99999 0.327 0.162 0.134 37863 3.338 3.442 0.388 0.016 8.351 0.785 0.370 0.138 0.147 0.112 38140 3.267 3.399 0.381 0.015 8.253 0.699 0.187 99999 0.131 0.087 38401 3.383 3.398 0.386 0.013 8.249 0.778 0.348 99999 0.146 0.122 38648 3.427 3.402 0.386 0.015 8.259 0.738 0.312 0.190 0.138 0.099 39145 3.234 3.249 0.360 0.011 7.909 0.627 0.145 99999 0.117 0.065 39392 3.193 3.228 0.368 0.015 7.864 0.582 0.134 0.116 0.109 0.068 39638 3.244 3.298 0.363 0.013 8.022 0.631 0.165 0.197 0.118 0.064 39885 3.255 3.268 0.360 0.014 7.953 0.643 0.182 99999 0.120 0.080 40132 3.224 3.252 0.361 0.014 7.917 0.594 0.143 99999 0.111 0.062 40378 3.211 3.259 0.368 0.012 7.933 0.602 0.142 0.203 0.113 0.070 40625 3.302 3.275 0.369 0.015 7.968 0.628 0.162 99999 0.117 0.072 40872 3.220 3.231 0.353 0.014 7.869 0.591 0.103 0.255 0.110 0.060 41119 3.298 3.281 0.363 0.014 7.983 0.666 0.176 0.185 0.125 0.079 41616 3.282 3.297 0.363 0.012 8.018 0.633 0.154 99999 0.118 0.075 41863 3.280 3.289 0.368 0.013 8.002 0.640 0.181 0.168 0.120 0.073 42111 3.321 3.258 0.373 0.013 7.930 0.650 0.176 0.183 0.122 0.077 42358 3.324 3.280 0.366 0.013 7.981 0.643 0.175 0.268 0.120 0.078 42606 3.363 3.278 0.363 0.015 7.976 0.613 0.159 0.224 0.115 0.076 42854 3.271 3.217 0.371 0.011 7.837 0.623 0.159 99999 0.117 0.067 43101 3.392 3.314 0.378 0.016 8.058 0.692 0.231 99999 0.129 0.087 43349 3.301 3.357 0.383 0.016 8.155 0.697 0.264 0.187 0.130 0.092 43597 3.370 3.372 0.386 0.013 8.190 0.711 0.284 99999 0.133 0.089 44095 3.374 3.356 0.382 0.015 8.155 0.680 0.253 0.227 0.127 0.081 44343 3.344 3.318 0.395 0.014 8.067 0.675 0.215 99999 0.126 0.083 44591 3.373 3.364 0.382 0.011 8.172 0.677 0.228 0.282 0.127 0.085 44839 3.306 3.346 0.380 0.014 8.132 0.661 0.213 0.112 0.124 0.078 45087 3.323 3.345 0.394 0.013 8.128 0.672 0.211 0.168 0.126 0.072 45335 3.230 3.164 0.354 0.012 7.719 0.485 0.032 99999 0.090 0.042 45583 3.268 3.226 0.362 0.017 7.859 0.552 0.065 99999 0.103 0.053 45830 3.191 3.095 0.353 0.013 7.565 0.483 0.055 99999 0.090 0.042 46078 3.168 3.106 0.360 0.014 7.589 0.402 0.038 99999 0.075 0.026 46574 3.203 3.229 0.378 0.014 7.864 0.507 0.053 99999 0.094 0.044 46822 3.211 3.191 0.366 0.013 7.779 0.509 0.071 99999 0.095 0.045 47069 3.260 3.229 0.381 0.014 7.866 0.552 0.079 99999 0.103 0.052 47317 3.242 3.232 0.371 0.013 7.872 0.543 0.086 0.308 0.101 0.049 47565 3.318 3.229 0.381 0.015 7.865 0.492 0.078 0.264 0.092 0.047 47812 3.250 3.165 0.359 0.013 7.722 0.467 0.056 0.167 0.087 0.037 48060 3.296 3.183 0.368 0.015 7.760 0.457 0.061 99999 0.085 0.043 48306 3.329 3.184 0.369 0.014 7.763 0.484 0.075 99999 0.090 0.039 48553 3.189 3.091 0.357 0.014 7.556 0.433 0.064 99999 0.081 0.037 49049 3.180 3.078 0.360 0.012 7.528 0.412 0.044 0.252 0.077 0.033 49296 3.239 3.105 0.360 0.012 7.586 0.406 0.056 0.168 0.075 0.034 49543 3.238 3.061 0.347 0.013 7.490 0.388 0.049 0.159 0.072 0.031 49791 3.110 3.058 0.349 0.012 7.484 0.382 0.042 0.209 0.071 0.029 50037 3.063 2.799 0.328 0.012 6.923 0.300 0.000 99999 0.055 0.025 50285 3.176 3.044 0.352 0.012 7.453 0.365 0.000 0.164 0.068 0.031 50532 3.130 2.917 0.335 0.012 7.176 0.327 0.000 0.134 0.061 0.023 50780 3.135 2.828 0.321 0.013 6.986 0.291 0.000 99999 0.054 0.024 51026 3.112 2.854 0.331 0.013 7.040 0.316 0.000 0.139 0.058 0.029 51522 3.087 2.893 0.337 0.012 7.125 0.308 0.001 99999 0.057 0.024 51770 3.096 2.891 0.334 0.015 7.120 0.311 0.000 0.145 0.057 0.030 52016 3.083 2.902 0.332 0.012 7.143 0.307 0.000 0.114 0.057 0.025 52262 3.040 2.823 0.321 0.013 6.973 0.294 0.000 99999 0.054 0.021 52508 3.077 2.911 0.329 0.012 7.162 0.326 0.000 99999 0.060 0.028 52754 3.083 2.931 0.331 0.013 7.207 0.315 0.000 99999 0.058 0.029 53001 3.106 2.943 0.325 0.014 7.232 0.338 0.000 99999 0.063 0.030 53247 3.110 3.004 0.339 0.012 7.365 0.350 0.000 99999 0.065 0.031 53493 3.159 3.113 0.344 0.014 7.606 0.374 0.040 0.147 0.069 0.029 53988 3.173 3.078 0.344 0.014 7.528 0.374 0.030 99999 0.069 0.035 54235 3.158 3.033 0.345 0.011 7.430 0.369 0.000 0.153 0.068 0.034 54480 3.098 3.041 0.338 0.014 7.447 0.359 0.057 99999 0.067 0.032 54727 3.064 2.984 0.333 0.012 7.321 0.346 0.000 0.157 0.064 0.030 54973 3.096 2.928 0.327 0.012 7.199 0.328 0.049 99999 0.061 0.028 55219 3.063 2.998 0.342 0.016 7.351 0.353 0.000 0.088 0.065 0.027 55465 3.016 2.886 0.318 0.013 7.109 0.315 0.000 99999 0.058 0.026 55713 2.968 2.748 0.312 0.013 6.816 0.271 0.000 99999 0.050 0.028 55959 2.891 2.692 0.296 0.013 6.697 0.259 0.000 99999 0.048 0.019 56456 3.177 2.978 0.337 0.012 7.307 0.316 0.000 99999 0.058 0.024 56701 3.247 3.233 0.361 0.015 7.873 0.429 0.038 99999 0.080 0.037 56948 3.124 3.079 0.346 0.013 7.529 0.354 0.000 99999 0.066 0.022 57195 3.101 2.944 0.337 0.014 7.234 0.291 0.000 0.187 0.054 0.021 57442 3.310 3.213 0.369 0.014 7.829 0.411 0.000 99999 0.076 0.030 57688 3.228 3.118 0.351 0.014 7.617 0.358 0.000 0.097 0.066 0.026 57934 3.249 3.133 0.348 0.014 7.650 0.387 0.036 99999 0.072 0.029 58181 3.227 3.249 0.365 0.017 7.910 0.395 0.027 0.110 0.073 0.029 58427 3.323 3.222 0.359 0.014 7.848 0.410 0.046 99999 0.076 0.034 58923 3.240 3.060 0.344 0.015 7.488 0.327 0.007 99999 0.060 0.024 59169 3.281 3.181 0.360 0.014 7.756 0.364 0.000 0.116 0.068 0.029 59417 2.982 2.620 0.291 0.013 6.547 0.201 0.000 0.083 0.037 0.015 59664 2.947 2.586 0.286 0.011 6.478 0.197 0.000 99999 0.036 0.021 59910 3.027 2.820 0.310 0.013 6.967 0.251 0.000 99999 0.046 0.018 60157 3.141 3.007 0.329 0.013 7.372 0.300 0.000 0.136 0.055 0.025 60404 3.155 3.091 0.344 0.015 7.556 0.327 0.028 99999 0.060 0.028 60652 3.311 3.213 0.351 0.015 7.830 0.373 0.029 99999 0.069 0.028 60899 3.201 3.179 0.350 0.017 7.753 0.373 0.039 99999 0.069 0.031 61397 3.343 3.206 0.360 0.016 7.812 0.375 0.008 0.108 0.070 0.030 61643 3.289 3.213 0.353 0.013 7.829 0.397 0.040 99999 0.074 0.031 61890 3.204 3.073 0.350 0.015 7.516 0.333 0.000 99999 0.062 0.027 62137 3.117 2.987 0.341 0.014 7.329 0.306 0.030 0.157 0.057 0.023 62384 3.199 3.070 0.350 0.013 7.510 0.352 0.020 99999 0.065 0.031 62631 3.251 3.146 0.352 0.014 7.680 0.367 0.044 99999 0.068 0.033 62878 3.262 3.132 0.353 0.014 7.648 0.383 0.053 99999 0.071 0.026 63125 3.341 3.167 0.357 0.015 7.726 0.377 0.036 99999 0.070 0.029 63373 3.263 3.224 0.360 0.014 7.854 0.437 0.060 99999 0.081 0.042 63869 3.361 3.252 0.375 0.015 7.916 0.446 0.037 0.111 0.083 0.035 64115 3.332 3.302 0.380 0.013 8.030 0.512 0.095 99999 0.096 0.049 64362 3.349 3.352 0.391 0.017 8.145 0.531 0.111 0.144 0.099 0.055 64610 3.357 3.380 0.398 0.017 8.209 0.584 0.147 0.141 0.109 0.060 64857 3.447 3.394 0.387 0.017 8.240 0.589 0.158 99999 0.110 0.067 65104 3.424 3.402 0.381 0.012 8.259 0.599 0.173 99999 0.112 0.062 65352 3.461 3.422 0.387 0.015 8.306 0.628 0.181 0.139 0.117 0.075 65599 3.345 3.259 0.365 0.014 7.932 0.440 0.131 0.187 0.082 0.042 65846 3.420 3.413 0.397 0.015 8.286 0.731 0.228 0.116 0.137 0.091 66344 3.313 3.371 0.389 0.016 8.188 0.816 0.403 99999 0.153 0.115 66592 3.355 3.377 0.383 0.015 8.201 0.849 0.508 0.241 0.159 0.137 66841 3.386 3.379 0.377 0.015 8.207 0.694 0.248 0.124 0.130 0.089 67090 3.269 3.386 0.380 0.015 8.222 0.774 0.357 99999 0.145 0.109 67338 3.365 3.436 0.386 0.017 8.337 0.937 0.828 99999 0.176 0.198 67586 3.439 3.445 0.399 0.017 8.358 0.982 0.858 0.272 0.184 0.198 67834 3.448 3.458 0.395 0.017 8.389 1.061 1.021 0.382 0.199 0.235 68083 3.386 3.355 0.398 0.017 8.152 1.051 1.312 99999 0.197 0.203 68331 3.367 3.382 0.393 0.014 8.213 1.162 1.728 99999 0.218 0.239