63 1001 Timo Keber, Tanja Schuck, Andreas Engel Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhoeferallee 1, 60438 Frankfurt/Main, Germany HALO | GhOST-MS | mixing ratios of long-lived and very short-lived tracers measured with an in-situ GC-MS instrument WISE 1 1 2017 10 21 2018 03 14 0 Mean sample time in UT seconds past midnight of flight date 10 1 1 1 1 1 1 1 1 1 1 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 H1301 [ppt] H1211 [ppt] H2402 [ppt] H1202 [ppt] CH3Br [ppt] CH2Br2 [ppt] CHBr3 [ppt] CH2BrCl [ppt] CHBrCl2 [ppt] CHBr2Cl [ppt] 37 ------------------------------------------------------------------------ WISE flight 16 on 21.10.2017 PRELIMINARY DATA ------------------------------------------------------------------------ Please inform the authors about the use of the data Before publication, the authors of the data have to give their consent Please adhere in all cases to the WISE data protocol Contact: Andreas Engel (an.engel@iau.uni-frankfurt.de, phone +49 69 798 40259) ------------------------------------------------------------------------ Calibration Scale, Precision, Accuracy and Detection Limit are given separately for each dependent variable Primary calibration reference flasks: "TO-Mutter" (UEA scales), "AGAGE H-218" (all other scales) Calibration Scales SIO-05 SIO-05 SIO-14 UEA-09 SIO-05 NOAA-Jul10-p NOAA-Dec09-p SIO-10-p UEA-11 UEA-11 ------------------------------------------------------------------------ CH3Br derived from H1211 using correlation based on balloon measurements in 2009 and 2011. CH2Br2 and CHBr2Cl derived using correlation from HALO PGS campaign 2015/2016 ------------------------------------------------------------------------ Instrument precision in [%] 0.99 0.49 1.49 7.58 4.22 0.67 2.21 9.16 3.43 2.22 Instrument precision in [ppt] 0.039 0.046 0.005 0.001 0.333 0.012 0.015 0.025 0.002 0.004 Use whatever precision is larger for each data point ------------------------------------------------------------------------ Accuracy of mixing ratios in calibration gas in [%] 0.6 0.3 0.8 25.0 NaN 4.9 17.3 5.8 20.6 6.3 ------------------------------------------------------------------------ Detection limit (S/N 3/1) in [ppt] per 100 mL air at STP 0.050 0.006 0.007 0.006 0.646 0.011 0.086 0.130 0.002 0.002 Values below detection limit are marked as 0.00 In case no measurements are available, the missing data value is used ------------------------------------------------------------------------ Sample integration time: 54 +- 1 seconds Values of t_sample are the mean of the sampling time interval ("integration time") ------------------------------------------------------------------------ Correction of analyte carry-over (memory effect): all substances Detector non-linearity: below measurement precision for all substances, no correction applied ------------------------------------------------------------------------ 2 UTC H1301 H1211 H2402 H1202 CH3Br CH2Br2 CHBr3 CH2BrCl CHBrCl2 CHBr2Cl [s] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] [ppt] 16952 3.387 3.601 0.395 0.015 8.724 1.174 99999 0.266 0.221 0.219 17202 3.211 3.308 0.367 0.015 8.044 0.519 0.154 0.252 0.097 0.052 17452 3.227 3.299 0.360 0.013 8.023 0.555 0.074 0.186 0.104 0.061 17700 3.168 3.213 0.345 0.012 7.830 0.492 0.061 0.223 0.092 0.052 17949 3.225 3.326 0.367 0.014 8.085 0.566 0.079 0.182 0.106 0.064 18197 3.222 3.257 0.356 0.014 7.927 0.533 0.070 0.195 0.099 0.057 18445 3.264 3.327 0.357 0.014 8.088 0.568 0.083 0.211 0.106 0.066 18707 99999 3.468 0.381 0.014 8.413 0.713 0.176 0.224 0.134 0.094 18970 3.259 3.404 0.365 0.014 8.264 0.623 0.129 0.188 0.116 0.076 19469 3.310 3.467 0.376 0.015 8.411 0.693 0.160 0.223 0.130 0.088 19717 3.322 3.491 0.384 0.015 8.466 0.703 0.171 0.218 0.132 0.090 21466 3.340 3.396 0.381 0.015 8.246 0.706 0.206 0.310 0.132 0.093 21715 3.313 3.374 0.380 0.014 8.196 0.689 0.221 0.236 0.129 0.091 21964 99999 3.406 0.378 0.013 8.269 0.713 0.229 0.264 0.133 0.092 22213 3.352 3.377 0.381 0.014 8.203 0.700 0.228 99999 0.131 0.088 22462 3.311 3.297 0.364 0.013 8.018 0.630 0.167 0.187 0.118 0.075 22712 99999 3.345 0.373 0.014 8.128 0.683 0.196 0.190 0.128 0.084 22961 99999 3.332 0.367 0.015 8.099 0.666 0.176 0.236 0.125 0.085 23210 99999 3.296 0.365 0.014 8.018 0.642 0.164 0.206 0.120 0.073 23459 3.301 3.285 0.362 0.013 7.992 0.631 0.152 0.193 0.118 0.075 23709 99999 3.185 0.357 0.011 7.767 0.543 0.081 0.172 0.101 0.053 23958 3.317 3.274 0.359 0.013 7.966 0.589 0.100 0.128 0.110 0.062 24458 3.282 3.295 0.359 0.014 8.015 0.617 0.105 0.193 0.115 0.066 24707 99999 3.278 0.366 0.015 7.975 0.608 0.115 0.207 0.114 0.066 24956 99999 3.330 0.367 0.014 8.094 0.634 0.116 0.226 0.119 0.071 25205 99999 3.349 0.369 0.015 8.137 0.663 0.148 0.231 0.124 0.074 25454 99999 3.376 0.375 0.014 8.200 0.671 0.137 0.204 0.125 0.072 25704 3.341 3.353 0.372 0.015 8.148 0.646 0.116 0.263 0.121 0.070 25953 3.332 3.355 0.378 0.014 8.151 0.652 0.124 0.263 0.122 0.069 26202 3.319 3.377 0.376 0.013 8.203 0.647 0.127 99999 0.121 0.067 26451 3.333 3.359 0.380 0.015 8.161 0.632 0.121 0.238 0.118 0.064 26951 3.261 3.302 0.374 0.014 8.030 0.597 0.082 0.212 0.112 0.058 27200 99999 3.330 0.373 0.015 8.094 0.624 0.109 0.215 0.117 0.064 27449 3.363 3.371 0.381 0.015 8.188 0.641 0.121 0.200 0.120 0.068 27698 99999 3.364 0.380 0.015 8.171 0.651 0.115 0.229 0.122 0.065 27947 99999 3.375 0.376 0.014 8.198 0.641 0.110 0.199 0.120 0.064 28196 99999 3.338 0.371 0.013 8.113 0.615 0.099 0.202 0.115 0.061 28445 3.302 3.337 0.370 0.014 8.110 0.621 0.093 0.233 0.116 0.060 28694 3.327 3.343 0.376 0.014 8.125 0.632 0.108 0.170 0.118 0.063 28943 3.343 3.338 0.374 0.014 8.112 0.633 0.096 0.178 0.118 0.059 29443 3.367 3.333 0.376 0.013 8.100 0.631 0.083 0.213 0.118 0.059 29692 3.329 3.356 0.376 0.014 8.155 0.636 0.113 0.182 0.119 0.063 29941 3.345 3.316 0.377 0.014 8.062 0.619 0.097 0.154 0.116 0.058 30191 3.296 3.297 0.366 0.014 8.018 0.588 0.088 0.133 0.110 0.055 30440 3.277 3.199 0.355 0.014 7.797 0.537 0.068 0.137 0.100 0.047 30689 99999 3.342 0.376 0.013 8.122 0.658 0.142 0.134 0.123 0.067 30939 3.276 3.217 0.358 0.014 7.837 0.545 0.078 0.152 0.102 0.049 31188 99999 3.221 0.355 0.014 7.848 0.534 0.078 0.148 0.100 0.047 31437 3.262 3.193 0.354 0.014 7.784 0.526 0.061 99999 0.098 0.048 31938 3.312 3.232 0.365 0.014 7.872 0.582 0.105 0.154 0.109 0.061 32186 3.366 3.314 0.369 0.014 8.057 0.634 0.150 0.166 0.118 0.067 32435 99999 3.336 0.370 0.014 8.108 0.650 0.153 0.164 0.122 0.071 32684 3.339 3.331 0.378 0.014 8.096 0.648 0.147 0.145 0.121 0.069 32933 99999 3.337 0.376 0.015 8.110 0.656 0.149 0.168 0.123 0.070 33182 3.382 3.349 0.371 0.015 8.138 0.650 0.158 0.168 0.121 0.070 33431 3.371 3.375 0.379 0.015 8.197 0.669 0.161 99999 0.125 0.070 33681 99999 3.390 0.381 0.013 8.232 0.723 0.189 0.151 0.135 0.079 33930 3.409 3.413 0.385 0.014 8.285 0.732 0.229 0.107 0.137 0.082 34429 99999 3.383 0.383 0.014 8.216 0.719 0.162 0.142 0.135 0.077 34679 3.373 3.395 0.380 0.015 8.244 0.706 0.157 0.206 0.132 0.074 34928 99999 3.369 0.374 0.014 8.183 0.697 0.154 0.156 0.130 0.071 35178 3.340 3.372 0.380 0.015 8.189 0.634 0.135 0.124 0.119 0.066 35426 3.393 3.346 0.370 0.014 8.131 0.647 0.165 0.173 0.121 0.069 35675 3.327 3.308 0.366 0.016 8.044 0.592 0.105 0.134 0.111 0.059 35924 3.298 3.273 0.359 0.015 7.965 0.499 0.047 0.224 0.093 0.035 36173 3.302 3.284 0.363 0.014 7.989 0.515 0.051 0.225 0.096 0.042 36422 3.260 3.227 0.359 0.013 7.861 0.498 0.058 99999 0.093 0.043 36920 3.221 3.142 0.342 0.014 7.670 0.438 0.030 99999 0.082 0.035 37169 3.197 3.099 0.340 0.012 7.575 0.430 0.049 0.179 0.080 0.037 37418 3.131 2.970 0.322 0.012 7.290 0.353 0.030 0.184 0.065 0.029 37667 99999 2.892 0.310 0.013 7.122 0.333 0.020 0.190 0.062 0.024 37917 3.010 2.801 0.309 0.011 6.928 0.301 0.021 0.194 0.056 0.023 38165 3.170 2.961 0.325 0.013 7.272 0.363 0.021 0.199 0.067 0.026 38414 3.006 2.746 0.296 0.011 6.810 0.291 0.000 0.152 0.054 0.021 38663 2.975 2.754 0.298 0.013 6.828 0.290 0.016 0.181 0.054 0.020 38913 3.004 2.707 0.292 0.011 6.728 0.286 0.000 0.233 0.053 0.020 39412 99999 2.669 0.290 0.011 6.650 0.267 0.000 0.150 0.049 0.018 39660 99999 2.662 0.289 0.012 6.635 0.270 0.015 0.158 0.050 0.020 39909 2.968 2.722 0.295 0.012 6.760 0.277 0.015 99999 0.051 0.020 40157 99999 2.944 0.323 0.011 7.235 0.349 0.000 0.201 0.065 0.024 40406 3.119 2.959 0.325 0.013 7.266 0.363 0.017 0.176 0.067 0.030 40655 2.987 2.828 0.306 0.013 6.986 0.314 0.018 0.170 0.058 0.024 40904 3.188 3.111 0.351 0.012 7.601 0.440 0.045 0.197 0.082 0.037 41152 3.117 3.030 0.335 0.013 7.423 0.384 0.036 0.173 0.071 0.032 41401 3.259 3.200 0.356 0.014 7.801 0.460 0.048 0.139 0.086 0.037 41900 3.223 3.217 0.356 0.012 7.838 0.455 0.031 0.145 0.085 0.039 42150 3.243 3.286 0.365 0.013 7.994 0.523 0.070 0.167 0.098 0.048 42400 3.232 3.307 0.366 0.013 8.042 0.552 0.094 0.164 0.103 0.056 42650 99999 3.262 0.361 0.013 7.940 0.521 0.080 0.174 0.097 0.048 42900 3.295 3.307 0.367 0.013 8.042 0.578 0.091 99999 0.108 0.053 43148 3.287 3.303 0.371 0.013 8.033 0.559 0.099 0.138 0.104 0.055 43398 99999 3.369 0.377 0.013 8.184 0.670 0.118 0.221 0.125 0.068 43647 99999 3.395 0.382 0.012 8.243 0.680 0.150 0.129 0.127 0.073 43897 3.389 3.451 0.386 0.012 8.372 0.979 0.687 0.274 0.184 0.167 44396 99999 3.465 0.390 0.012 8.406 0.812 0.394 0.211 0.152 0.116 44647 3.403 3.441 0.389 0.013 8.351 0.926 0.567 0.221 0.174 0.139 44897 3.382 3.460 0.391 0.015 8.394 0.936 0.561 0.341 0.176 0.143 45147 3.375 3.457 0.393 0.015 8.387 0.787 0.374 0.197 0.147 0.111 45398 99999 3.472 0.395 0.015 8.421 0.937 0.818 0.289 0.176 0.166 45648 3.350 3.544 0.401 0.016 8.591 1.079 1.167 0.329 0.203 0.222 45898 99999 3.560 0.401 0.017 8.628 1.070 1.208 0.328 0.201 0.216 46148 3.416 3.569 0.409 0.016 8.648 1.042 1.139 0.408 0.196 0.213 46398 99999 3.808 0.403 0.017 9.222 1.034 1.152 0.296 0.194 0.209