46 1001 Eric Foerster (Eric.Foerster@kit.edu) Institute of Meteorology and Climate Research (IMK), Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe, P.O. Box 3640, Germany 1 | HALO | HKMS | VOC data measured with instrument HKMS (HALO Karlsruher Mass Spectrometer) a Proton Transfer Reaction - Mass Spectrometer onboard the research aircraft HALO EM-EU-05 1 1 2017 07 17 2020 03 04 0 Time; seconds after midnight (UTC); [s] 20 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 FOR; Formaldehyde, volume mixing ratio; [pptV]; quantified by signal integration on protonated FOR (m/z = 31) FOR_prec; Formaldehyde, precision; [pptV]; FOR_lod; Formaldehyde, humidity dependent in-flight detection limit; [pptV] MET; Methanol, volume mixing ratio; [pptV]; quantified by signal integration on protonated MET (m/z = 33.2) MET_prec; Methanol, precision; [pptV]; MET_lod; Methanol, humidity dependent in-flight detection limit; [pptV] ACN; Acetonitrile, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACN (m/z = 42) ACN_prec; Acetonitrile, precision; [pptV]; ACA; Acetaldehyde, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACA (m/z = 45) ACA_prec; Acetaldehyde, precision; [pptV]; ACE; Acetone, volume mixing ratio; [pptV]; quantified by signal integration on protonated ACE (m/z = 59) ACE_prec; Acetone, precision; [pptV]; ISO; Isoprene, volume mixing ratio; [pptV]; quantified by signal integration on protonated ISO (m/z = 69) ISO_prec; Isoprene, precision; [pptV]; BEN; Benzene, volume mixing ratio; [pptV]; quantified by signal integration on protonated BEN (m/z = 79) BEN_prec; Benzene, precision; [pptV]; TOL; Toluene, volume mixing ratio; [pptV]; quantified by signal integration on protonated TOL (m/z = 93) TOL_prec; Toluene, precision; [pptV]; XYL; Xylene, volume mixing ratio; [pptV]; quantified by signal integration on protonated XYL (m/z = 107) XYL_prec; Xylene, precision; [pptV]; 4 AT THE MOMENT NO VOC DATA FOR EM-EU-05 AVAILABLE Unfortunately a mandatory part of the instrument (drift tube heating and temperature sensor) did not work correctly during the ~90 % of the flight. No reliable data available. Nonetheless, after some considerations, it could be possible to restore 80-90 % of the flight data. We just need an estimate/assumption for the drift tube temperature (~ HKMS Rack temperature). Then we can readjust our calibrations and with some larger errors the data can be made available. 8 Temporal resolution is ca. -9999 Hz. FileName: EMERGE-EU-05_2017-07-17_HKMS_0VOCs_V03.ames Version: V03 ChangeLog1: V01->V02: 20181025, Preliminary to first final data. ChangeLog2: V02->V03: 20190503, Updated humidity correction, calculation of precision and accuracy; Applied bottle drift correction for MET and FOR; Applied humidity dependent background subtraction of FOR; Added VOC dependent LODs. Data status is unspecified. Expect changes in future. [s] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] [pptV] Time FOR FOR_prec FOR_lod MET MET_prec MET_lod ACN ACN_prec ACA ACA_prec ACE ACE_prec ISO ISO_prec BEN BEN_prec TOL TOL_prec XYL XYL_prec 36023 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999